Practice_Quiz_22

Practice_Quiz_22 - Practice Quiz 22(1 Provide the products of the following reactions as requested CHO HO H(A H H H OH OH OH CH2OH COOH Br2 H2O HO

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OH CH 2 OH OH H COOH H H H OH HO OH COOH OH H COOH H H H HO HO (A) Br 2 H 2 O (B) O CH 3 O H CH 3 OCH 2 H OCH 3 CH 3 O H H H 3 O + H 2 O complete open-chain structure OCH 3 H (C) OH CH 2 OH OH H CHO H H H HO Practice Quiz 22 (1) Provide the products of the following reactions as requested. open-chain Fischer structure HNO 3 HO open-chain Fischer structure OH CH 2 OH OH H CHO H H H OH HO CH 2 OCH 3 CHO OH H OCH 3 CH 3 O CH 3 O H H H
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(2) Supply the missing structures, as requested, in the scheme below. CHO CH 2 OH OH H + CH 3 OH OH HO OH H H H H D-(+)-glucose β -D-glucopyanose methyl β -D-glucopyanoside CH 3 OSOCH 3 O = O /HO - excess O OH HOCH 2 HO HO H OH O OH HOCH 2 HO HO H OCH 3 O O CH 3 OCH 2 CH 3 O CH 3 O H OCH 3 CH 3
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only III CHO CH 2 OH OH HO H H CHO CH 2 OH OH H HO H HO H CHO CH 2 OH OH H HO H HO H CHO CH 2 OH OH H HO H H OH CH 2 OH OH H H HO OH H H OH CHO CH 2 OH OH H H HO OH H H CHO CH 2 OH OH H H HO H H OH CHO HO HO CH 2 OH OH H H HO H H CHO HO HO I II III IV V VI VII VIII (3)
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This note was uploaded on 01/23/2011 for the course CHEM 322BL taught by Professor Singer during the Spring '07 term at USC.

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Practice_Quiz_22 - Practice Quiz 22(1 Provide the products of the following reactions as requested CHO HO H(A H H H OH OH OH CH2OH COOH Br2 H2O HO

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