L14 15OChem145s10

L14 15OChem145s10 - Lectures 14 & 15: Introduction to...

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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Reading assignment : OGC §7.1-7.4; §7.6 (excluding reactions); Learning objectives: • Recognize organic molecules of the following types and sketch their structures: • Alkanes Alkenes Alkynes Alcohols • Ethers Aldehydes Esters Ketones • Carboxylic acids Amines Amides Haloalkanes • Aromatic hydrocarbons • Distinguish isomers of organic molecules • Constitutional isomers cis-trans isomers Lectures 14 & 15: Introduction to Organic Chemistry Figures marked “from Solomons” are from T. W. Graham Solomons, Fundamentals of Organic Chemistry, Fifth Ed. John Wiley & Sons, New York, 1997. 1
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Categories of Organic Compounds · C x H y alk a nes: C-C single bonds alk e nes: C=C double bond alk y nes: C C triple bond · C x H y O z alcohols, aldehydes, carboxylic acids, ethers, ketones, esters · C x H y halogen z chlorides, bromides, etc. · C x H y N z amines · C x H y N z O w amides 2
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Characterized by C-C single bonds Chain alkanes: C n H 2n+2 • a.k.a. normal alkanes sp 3 hybridization of C • 4 single σ bonds to each C — saturated • rotation about the σ bond Alk a nes [OGC §7.2] Note: hydrogen forms only one primary bond OGC Figure 7.2 7.2 3
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Cyclic alkanes: C n H 2n cyclopropane, cyclobutane, • cyclohexane, etc. Alk a nes [OGC §7.2] OGC Figure 7.6 4
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Branched alkanes: C n H 2n+2 • Alkane-like side groups • Drop -ane and replace with –yl Alk a nes [OGC §7.2] 7.2 5
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Rules for naming alkanes • Find longest C-chain • Number the C atoms • Identify the side groups (if any) • If more than one identical alkyl group is attached to the chain, identify the number using a prefix di- (two), tri- (three), tetra- (four), penta- (five) , etc. • If several types of alkyl groups appear, name them in alphabetical order Alk a nes [OGC §7.2] 6
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Lectures 14-15, spring 2010 ENGR 145, Chemistry of Materials Case Western Reserve University Naming alkanes: example 6-C chain hexane #2: methyl #4: methyl #4: ethyl 4-ethyl-2,4-dimethylhexane Alk a nes [OGC §7.2] 7.1 7
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This note was uploaded on 01/30/2011 for the course EMSE 103 taught by Professor Ggh during the Spring '10 term at Case Western.

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L14 15OChem145s10 - Lectures 14 & 15: Introduction to...

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