Sp09FinalQues - NAME (Print): _ SIGNATURE: _ Chemistry 310N...

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Chemistry 310N Dr. Brent Iverson Final May 18, 2009 NAME (Print): _____________________________ SIGNATURE: _____________________________ Please Note: This test may be a bit long, but there is a reason. I would like to give you a lot of little questions, so you can find ones you can answer and show me what you know, rather than just a few questions that may be testing the one thing you forgot. I recommend you look the exam over and answer the questions you are sure of first , then go back and try to figure out the rest. Also make sure to look at the point totals on the questions as a guide to help budget your time. Note: You must have your answers written in pen if you want a regrade!!!! Please print the first three letters of your last name in the three boxes For synthesis problems GO FOR PARTIAL CREDIT EVEN IF YOU DO NOT KNOW THE ENTIRE ANSWER!!!WRITE DOWN WHAT YOU DO KNOW IS IN THE REACTION SEQUENCE SOMEWHERE. YOU WILL GET PARTIAL CREDIT IF IT IS CORRECT
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Honor Code The core values of the University of Texas at Austin are learning, discovery, freedom, leadership, individual opportunity, and responsibility. Each member of the University is expected to uphold these values through integrity, honesty, trust, fairness, and respect toward peers and community. (Your signature)
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CH 3 CH 2 - H R 2 C C H H H -N( i- C 3 H 7 ) 2 RC C H COR' O RC H 2 CR' O RC H 2 CH O RC H 2 CCl O RC H 2 RCH 2 O H HO H ROC O COR' O C H 2 RC O COR' O C H 2 RC O CR' O C H 2 H 4 N CO- H O R RCH 2 O H 2 H 3 O H -Cl 10 51 -7 Compound pK a 3-5 15.7 16 18-20 11 23-25 18-20 13 15-19 40 Carboxylic acids ! -Dicarbonyls ! -Ketoesters ! -Diesters Water Alcohols Acid chlorides Aldehydes Ketones Esters LDA Alkanes Terminal alkynes 25 Terminal alkenes 44 9.2 Ammonium ion Hydronium ion Hydrochloric acid Protonated alcohol -2 -1.7 C O R -0.5 Protonated Amide N H 3
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Signature_________________________ 2. (14 points) Suppose a relative of yours is having an MRI. In no more than four sentences, explain to them what is happening when they have the MRI scan. We will be looking for a minumum of 7 key points here. 3. (8 pts) On the left is drawn the Lewis structure of a simple amide. Draw the two next most important contributing structures in the spaces provided. Be sure to show all lone pairs and formal charges. Place arrows on the two structures on the left to indicate how you are moving electrons to create the structure immediately to their right. H C H H C O N H H 3. (10 pts) Because of pi delocalilzation,many of the atoms in the molecules below are predicted to be in the same plane. On the structures below, circle all the atoms that you believe will be located the same plane at equilibrium. Do not circle atoms that are in the same plane only temporarily as their bonds are rotating freely at room temperature. 1.
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Sp09FinalQues - NAME (Print): _ SIGNATURE: _ Chemistry 310N...

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