Sp06Exam1Ques - NAME(Print SIGNAT URE Chemistry 310N Dr...

Chemistry 310N
Dr. Brent Iverson
1st Midterm
Feb. 23, 2006
NAME (Print): _____________________________
SIGNATURE: _____________________________
Please Note: This test may be a bit long, but there is a reason. I would like to give you a lot
of little questions, so you can find ones you can answer and show me what you know, rather
than just a few questions that may be testing the one thing you forgot. I recommend you
look the exam over and answer the questions you are sure of first , then go back and try
to figure out the rest. Also make sure to look at the point totals on the questions as a
guide to help budget your time.
Note: You must have your answers written in
pen if you want a regrade!!!!
Please print the
first three letters
of your last name
in the three boxes
For synthesis problems GO FOR PARTIAL CREDIT EVEN IF YOU DO NOT KNOW
THE ENTIRE ANSWER!!!WRITE DOWN WHAT YOU DO KNOW IS IN THE
REACTION SEQUENCE SOMEWHERE. YOU WILL GET PARTIAL CREDIT IF IT IS
CORRECT

10
9
8
7
6
5
4
3
2
(22)
(22)
(32)
(5)
(5)
(5)
(5)
(5)
(12)
(21)
(19)
(18)
(20)
(13)
(13)
(16)
(233)
11
1
Page Points
Total
T
Score
HW
12
13
14
15
16

RCH
2
OR
ArCH
3
R
2
C=CHR
RCH
3
RCH
RC CH
O
RCOH
O
RCCH
3
ROH
RCH
2
Cl
RCH
2
Br
RCH
2
I
RCH
2
OH
RCH
2
F
O
O
O
RCH
2
R
R
3
CH
O
R
2
NH
RCCH
2
R
R
2
C=CRCHR
2
R
2
C=CH
2
RCOCH
3
RCOCH
2
R
ArOH
O
H
2
C CH
2
RCH
2
NR
2
* Values are relative to tetramethylsilane. Other atoms within the
molecule may cause the signal to appear outside these ranges.
Type of Hydrogen
(R = alkyl, Ar = aryl)
Type of Hydrogen
(R = alkyl, Ar = aryl)

H
O
O
Br
O
OH
HO
HO
HOH
2
1. (4 pts each) In the space provided, write the IUPAC name (including stereochemistry where
appropriate) for the following two molecules:
OH
O
HO
HO
HO
HOH
2
C
OH
O
OH
OH OH
HO
O
OH OH
HO
OH
H
O
OH
OH
OH
HO
OH
Signature_________________________
Pg 1 _____________(22)
2. (4 pts) In the space provided, draw the following molecule:
( E )-5-Oxo-2-hexenal