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Unformatted text preview: L 2 and substitute into the expression of the Hamiltonian Angular Momenta in polar coordinates Schroedinger Equation for a Rigid Rotor Schroedinger Equation for a Rigid Rotor Eigenvalues Spacing between Eigenvalues is NOT constant: it increases with angular momentum J Absorption frequencies of the order of ~ 210 10 to 10 11 Hz in diatomic molecules microwave region n Spacing between Eigenvalues is NOT constant: it increases with angular momentum J Absorption frequencies of the order of ~ 210 10 to 10 11 Hz in diatomic molecules microwave region n n = 2B ( J+1) with B = rotational constant...
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This note was uploaded on 02/06/2011 for the course CHE 110A taught by Professor Mccurdy during the Fall '09 term at UC Davis.
 Fall '09
 Mccurdy
 Atom, Mole

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