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Unformatted text preview: TWO INTERACTING ELECTRONS: NO SEPARATION OF VARIABLES 1 and 2 are written as products of known functions . Note that each depends only on r 1 OR r 2 , not on both r 1 AND r 2 1 and 2 are basis functions; c 1 and c 2 are variational parameters to be determined is our trial wavefunction Overlap matrix elements Hamiltonian matrix elements Secular determinant energy c 1 , c 2 wavefunction Secular determinant energy c 1 , c 2 wavefunction Special cases: E = Natural units:...
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This note was uploaded on 02/06/2011 for the course CHE 110A taught by Professor Mccurdy during the Fall '09 term at UC Davis.
 Fall '09
 Mccurdy

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