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SCAN0010 - Practice 15 — Substitution a" Provide the...

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Unformatted text preview: Practice 15 — Substitution a" Provide the products of the following Show the correct curved arrow mech NaCN 1- \/\/Br —’ acetone acetone NaCN ‘> '1 acetone TSO H 6. Nal '2 _, T50 H acetone ' 336% ination 4 Be sure to show all appropriate stereochemistry. II 1 — 12. 3%: TsO l—l H20 8. . NaNI—i2 TsO ’H DMSO H ‘Br 6 NaOH 9. H20 HéBr 10 G Nal “b H20 H \Br 11- NaOMe MeOH H\Br ‘ NH3 12. ‘. DMF For the following pairs of reactions predict which will be faster and explain why. 13. a) Y0 b) 14. a) X Br H20 heat NaNa EtOH ’ YNS b) Br EEC: VOH Ph 6 Ph Br 15.61) VKA Mi. b) \/\/\/Br NaSH, SH \AA 16' a) \/\Br WNZCN \/\CN 17. a) NaOH \/\OH \/\Br H20 b) O NaOZCCHs \/\Br *, wok H20 13' a) \/L NaCN Br W 5) VLCN \/\Br NaCN \/\CN ...
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