L08s08 orbitals

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Unformatted text preview: CHEM 1A L8: "QM Orbitals" Absorption and Emission Spectra Review E=h E=h A.Pines,M.Kubinec,UCB L8-7 Wave Functions Energy: (x) = ET (x) 82m dx2 d2 n n x A sin L 82m L h2 = ET (x) 2 (x) 2(x) En 16 - h2 n=4 n=3 9 En = 2004 M.Kubinec h2n2 8mL2 n=2 n=1 4 1 L08-1 L19-9 2004 M.Kubinec ChemQuiz 6.4 To which energy-level energyscheme does the emission spectrum correspond? A) 2004 M.Kubinec B) C) L08-2 ChemQuiz 6.4 Solution B) A) C) 2004 M.Kubinec L08-3 2004 M. Kubinec 1 CHEM 1A L8: "QM Orbitals" H-Atom, One-Electron Ions Onen=1 l = 0 (s) (s ml = 0 n=2 l = 0 (s) (s ml = 0 Radial Node n=2 ml = -1, +1 l = 1 (p) (p ml = 0 z - 2px Angular Node z 2py + z y x + 2pz z 1s + z 2s + - + y x - y y x y L9-5 x x n = 3 l = 0, 1, 2 A.Pines,M.Kubinec UCB 3s, 3p, 3d Orbitals A.Pin...
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This note was uploaded on 04/03/2008 for the course CHEM 1A taught by Professor Nitsche during the Spring '08 term at University of California, Berkeley.

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