Synthesis Chart - 2 SO 4 In some reactions it is used for...

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Synthetic chart Alkanes Haloalkanes Alkenes Organometallics Alcohols 1 o 2 o 3 o Aldehydes Ketones Carboxylic acids H 2 , Pd/C X = Cl, Br Mg, Et 2 O * 1. NaBH 4 2. H 3 O + MnO 4 - or Cr 2 O 7 2- MnO 4 - or Cr 2 O 7 2- 1. R-MgX 2. H 3 O + 1. NaBH 4 2. H 3 O + X 2 , light or conc. H 2 SO 4 , CO 2 HX or X 2 H 3 O + Alkynes H 2 , Lindlar's catalyst H 2 , Pd/C PCC, CH 2 Cl 2 * N.B. CH 2 Cl 2 and Et 2 O are just solvents, they do not participate in the reaction. H 3 O + is dilute aqueous acid (e.g., 10% H
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Unformatted text preview: 2 SO 4 ). In some reactions, it is used for workup, in others, it is an acid catalyst. Ester Amide Acid Chloride or Anydride ROH, H + H 3 O + , ∆ H 2 O ROH RNH 2 1. LiAlH 4 2. H 3 O + MnO 4- or Cr 2 O 7 2-or PCC,CH 2 Cl 2 * NaOH (cold, dilute), or H 2 O...
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This note was uploaded on 02/14/2011 for the course CHEM 1AA3 taught by Professor H during the Spring '08 term at McMaster University.

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