These substituted benzyltin dichloride were

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Unformatted text preview: e crystal X-ray diffractometric technique was used to obtain their molecular structures. 137 23rd-25th June 2010 3rd ICYC 2010 Universiti Sains Malaysia INO-P11 SYNTHESIS AND CHARACTERIZATION OF (E)-1-((2-AMINO-5NITROPHENYLIMINIO)METHYLNAPHTHALEN-2-OLATE Abeer Mohamed Farag, Siang Guan Teoh and Hasnah Osman School of Chemical Sciences, Universiti Sains Malaysia, 11800 Pulau Pinang, Malaysia E-mail: [email protected] Schiff bases have received much attention because of their potential applications in various pharmacological activities, as noted by their anticancer, anti -HIV, antibacterial and antifungal properties. In addition, some of them may be used as analytical reagents for the dete rmination of trace elements. In this work, we report the synthesis and characterization of (E) -1-((2-amino-51 nitrophenyliminio)methylnaphthalene-2-olate. This ligand was synthesized and characterized by FTIR, H 13 and C NMR, and single crystal X-ray crystallography. The single crystal XRD result show that the compound is zwitterionic and exists in a trans configuration about the C=N bond. INO-P12 SYNTHESIS AND STRUCTURAL STUDY OF OXIDOVANADIUM(IV) AND OXIDOVANADIUM(V) COMPLEXES Wong Hon Wee and Lo Kong Mun Department of Chemistry, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia E-mail: [email protected] Six new oxyvanadium(V) complexes were prepared from the reactions of vanadyl sulfate with Schiff base ligands derived from substituted pyruvic acid and substituted benzoic acid hydrazide [X CH2(COOH)C=NNHCOC6H4Y, X = H, CH3; Y = H, Cl, Br, NO2 and NH3]. The resulting vanadium(V) complexes were obtained as a resulting of oxidation of the oxovanadium(IV) ion. The complexes were characterized by IR and NMR spectroscopies. The molecular structures of the complexes were determined by single crystal X-ray crystallography. The vanadium(V) atom in the resulting complexes were found to be N,Ochelated by the benzohydrazidate anion a nd O,N,O’-chelated by the 2-(ben...
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This note was uploaded on 02/17/2011 for the course CHEMISTRY 101 taught by Professor Csr during the Spring '11 term at University of Louisville.

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