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Unformatted text preview: by Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy (SEM-EDX), Fourier Transform Infrared Spectrum (FTIR), X-Ray Diffraction (XRD), Thermal Gravimetric Analysis (TGA), and Brunner Emmett Teller Surface Scan (BET). Meanwhile, the methyl esters produced were analysed by using Gas Chromatography (GC) analy sis. The manipulative variables studied for this research are the oil/methanol molar ratio, types of catalyst and the weight of catalyst which were used to carry out the transesterification reaction. The optimal conditions for the oil/methanol molar ratio were found to be 1:48 (normal rice husk ash). The optimal condition for the amount of catalyst used was 30 wt. % which produced the yield of 75.2 % of methyl esters. 122 3rd ICYC 2010 Universiti Sains Malaysia 23rd-25th June 2010 ORAL PRESENTATION (INORGANIC)
INO-O1 SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL ACTIVITIES OF SOME INDOLE SCHIFF BASES AND THEIR METAL COMPLEXES
1 Mohamed Mustafa M, Hapipah MA, Mahmood Ameen A 1 2 2 Department of Chemistry, University Malaya, Kuala Lumpur Department of molecular medicine, Faculty of medicine, University Malaya, Kuala Lumpur E-mail: email@example.com 1 Tryptamine Schiff bases were prepared by the condensation reaction of ethanolic solution of Tryptamine with Salicylaldehyde (TS), 5-Chlorosalicylaldehyde (TCS) and 5-Nitrosalicylaldehyde (TNS). The ligands were coordinated to Cu(II), Ni(II), and Zn(II) by the reaction of metal acetates with the corresponding ligand in a 1 : 2 metal to ligand ratio. The solid products formed was collected, washed with ethanol and recrystallized from DMF. All the ligands and complexes p repared have been 1 13 characterized by spectroscopic methods using IR, H, and C NMR, UV-Vis, and mass spectra. Elemental C H N analysis was carried out, and metal content was determined using atomic absorption spectroscopy. X-ray diffraction crystallography was done for the ligand 2-[2-(1H-indol-3-yl) ethyliminiomethyl]-4-nitrophenolate (TNS) and shows that it was exists in the zwitterionic f...
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This note was uploaded on 02/17/2011 for the course CHEMISTRY 101 taught by Professor Csr during the Spring '11 term at University of Louisville.
- Spring '11