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628Fa07_Ex4 Key - 1(48 pts Write complete structural...

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1.(48 pts) Write complete structural formcllas for the MAJOR organic product or missing reactant in the following reactions. 1) NaNH2 CH3CH2CFCH - 2) 0 - 0 0 3) H30 , workup KOH - " 2 0 u ROOR
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w 1) Br2, CCI, * 2) 2NaNH2 liq. NH3 1) OsO, + enantiomer 2) H2S HO 1) NaNH2 liq. NH3 - C=CCH2CH3 2) CH3CH2Br
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+ HCI 11.(4 pts) Give the correct IUPAC name for the compound below.
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111.(10 pts) Write detailed step-by-step mechanisms for the CHCI, KOH , : CC12 +el* " 2 0 4' following reactions.
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IV. (1 0 pts) Devise practical laboratory synthesis of the following compounds. Specify all necessary reagents, solvents and reaction conditions. from f l c l
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V.(28 pts) Circle the best answer. a.
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