CHE 637-Unit 1-pt.2_student

CHE 637-Unit 1-pt.2_student -...

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!"#$ & ’ ()*$ + , -#./.0#1)/ 233/#1)4." .5 67#"89:2/;8<=;89: >8$."89 !"#$%&’( *’+&,+*’- ./0*1&2#, .3&(.3#4" 567689 +*4#:*’ ; < = .> ?@A N HO H 3 C O P O O O O H H = C O H R N HO H 3 C OH OH H Pyridoxine (Vitamin B 6 ) Pyridoxal phosphate (PLP), derivative of Pyridoxine = cofactor 676 ("0+"( #( $&B#$4&0 *’ C*&$3":*$#, 0"#$%&’( *’+&,+*’- 40#’(B"0 &B #’ #:*’& -0&D. 5$&B#$4&0( #0" :&,"$D,"( D("1 C/ "’E/:"( 4& 3",. 43": $#00/ &D4 # 0"#$%&’8> F/.*$#, 0"#$%&’G H"#:*’#%&’ &B #:*’& #$*1(9 *’+&,+"( B&0:#%&’ I C0"#J1&K’ &B ("+"0#, *:*’"( 5’&4" #,, ’*40&-"’( #0" .0&4&’#4"1 *’ C&1/9 B&0 (*:.,*$*4/=J"". ’"D40#,8 -#./.0#1)/ 233/#1)4." .5 67#"89:2/;8<=;89:?8$."89@ 1."$A B81<)"#97C
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D8)14." EC 2;;#4." .5 F/#;89C G<8 H#I0 D8)14." J8"8*)/ D8)14."C L#J" #,J"’"( 5-"4 :*24D0" &B 5M8 I 5N8 *(&:"0(9 *B #. .,*$#C,"8 O,*1" P ’"D40#, :&,"$D," 3#+*’- ’"-#%+" Q #1R#$"’4 4& .&(*%+" 3"4"0&#4&:> 63&(.3&0D( /,*1"(G S $#,,"1 .3&(.3&0#’"(9 S 3#( 0"(&’#’$" (40D$4D0"(9 S 3#( T@ ","$40&’( #0&D’1 .3&(.3&0D(9 6 *( *’ U 01 ."0*&1 (& 3#( 1 &0C*4#,( S ’D$,"&.3*,*$ #4 Q I ","$40&.3*,*$ #4 6 D8)14." EC 2;;#4." .5 F/#;89C G<8 H#I0 D8)14." 1."$A V1+#’4#-" &+"0 :&(4 #,J"’" (/’43"(*( W J’&K K3"0" 1&DC," C&’1 K*,, C" *’ .0&1D$4 $&:.#0"1 MT 50"#00#’-":"’4 &B $#0C&$#%&’8 &0 C&43 MT I MX 5:D,%.," .0&1D$4( K3"’ 1*Y"0"’4 ! =3/10&-"’( #0" #+#*,#C," B&0 0":&+#,8 B81<)"#97 .5 H#I0 D8)14."C Z*[- 0"#$%&’ "#(/ 4& $#00/ &D49 CD4 :D(4 :#J" 43" /,*1" 5’&4 $&::"0$*#,,/ #+#*,#C," C"$#D(" 4&& D’(4#C,"8
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D8)14." EC 2;;#4." .5 F/#;89C G<8 H#I0 D8)14." 1."$A (*83)*)4." .5 =/#;8C \ ] X 0"#$%&’ &B .3&(.3*’" K*43 #,J/, 3#,*1" 5:D(4 3#+" #4 ,"#(4 T ^ #,&’- K*43 43" T 7_8 4& .0&1D$" .3&(.&’*D: (#,4 H".0&4&’#%&’ &B .3&(.3&’*D: (#,4 K*43 # (40&’- C#("> M’1 &B J"4&’"‘#,1"3/1" 0"#$%+*4/a&’ 4& $#0C&2/,*$ #$*1 1"0*+#%+"(b K)*L.M=/#1 21#;9 N O8*#P)4P89 QRS1/8.3<#/#1 2;;#4.", T/#7#")4." )$ 21=/ K)*L." O R OH O R Cl O R O O R OR O R NR 2 R O carboxylic acid acid (or acyl) chloride anhydride ester amide C N R nitrile CA derivatives V,, 3#+" ccc &2*1#%&’ (4#4" #4 $#0C&’/, Q 50"$#,, #,1"3/1"d( &2*1#%&’ (4#4" #4 $#0C&’/, Q PeT9 J"4&’"d( &2*1#%&’ (4#4" #4 $#0C&’/, Q P eX8 M2G $#,$D,#%&’(G
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K)*L.M=/#1 21#;9 , (*.38*489 V,, $#’ C" 3/10&,/E"1 5C0"#J #.#04 K*43 K#4"08 4& $#0C&2/,*$ #$*1 U$*S1$S*8 .5 KA2 > *’4"0:&,"$D,#0 ^=C&’1*’- C"4K""’ f^ .0&4&’( I $#0C&’/, &2/-"’ &B ’"*-3C&0*’- :&,"$D,"g 43*( :#J"( Q>V> ,"(( .&,#0 43#’ "2."$4"1 *’ ,*hD*1 .3#(">
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CHE 637-Unit 1-pt.2_student -...

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