HW6 - x1 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: x1 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00 GE/RT 0.00 ­0.09 ­0.17 ­0.24 ­0.31 ­0.38 ­0.43 ­0.47 ­0.51 ­0.53 ­0.55 ­0.55 ­0.55 ­0.53 ­0.50 ­0.45 ­0.39 ­0.32 ­0.23 ­0.12 0.00 ln(g1) ­1.80 ­1.70 ­1.59 ­1.47 ­1.36 ­1.24 ­1.12 ­1.00 ­0.88 ­0.76 ­0.65 ­0.54 ­0.44 ­0.35 ­0.26 ­0.19 ­0.12 ­0.07 ­0.03 ­0.01 0.00 ln(g2) 0.00 0.00 ­0.01 ­0.03 ­0.05 ­0.09 ­0.13 ­0.19 ­0.26 ­0.35 ­0.45 ­0.57 ­0.71 ­0.86 ­1.04 ­1.24 ­1.46 ­1.71 ­1.98 ­2.27 ­2.60 0.00 -0.50 -1.00 -1.50 -1.80 -2.00 -2.50 -3.00 0.00 0.10 0.20 0.30 0.40 Column C Column D Column E -2.60 -1.80 -2.60 20 0.30 0.40 0.50 X1 0.60 0.70 0.80 0.90 1.00 MeOH(1) H2O(2) Antoine coefficints & Psat at given T T (d C) A B C 60 16.58 3638.27 239.5 60 16.39 3885.7 230.17 Pst(kPa) 83.99 20.01 Margules coefficients A12 A21 P (kPa) 19.9530 39.2230 42.9840 48.8520 52.7840 56.6520 60.6140 63.9980 67.9240 70.2290 72.8320 84.5620 x1 0.0000 0.1686 0.2167 0.3039 0.3681 0.4461 0.5282 0.6044 0.6804 0.7255 0.7776 1.0000 y1 0.0000 0.5714 0.6268 0.6943 0.7345 0.7742 0.8085 0.8383 0.8733 0.8922 0.9141 1.0000 Experimental values gamma1 gamma2 ln(g1) 0.9973 1.5827 1.0106 0.4591 1.4803 1.0236 0.3923 1.3288 1.0723 0.2843 1.2540 1.1085 0.2264 1.1706 1.1543 0.1575 1.1047 1.2297 0.0995 1.0569 1.3075 0.0553 1.0380 1.3459 0.0373 1.0283 1.3785 0.0279 1.0194 1.4060 0.0192 1.0068 0.0068 ln(g2) ­0.0027 0.0106 0.0233 0.0698 0.1030 0.1435 0.2068 0.2681 0.2971 0.3210 0.3408 GE/RT ­0.0027 0.0862 0.1033 0.1350 0.1484 0.1498 0.1501 0.1395 0.1203 0.1084 0.0907 0.0068 Experimental data & calculated values 0.8000 0.7000 0.6000 0.5000 0.4000 0.3000 0.2000 0.1000 0.0000 -0.1000 0.0000 f(x) = -0.16x + 0.67 R² = 0.74 Column G Column H Column I Column J Linear Regression for Column J Column L Column M Column N 0.2000 0.4000 x1,y1 0.6000 0.8000 1.0000 argules coefficients 0.67 0.51 Calculated values G /RT gamma1 gamma2 0.0000 1.95 1 0.0898 1.53 1.02 0.1074 1.44 1.04 0.1310 1.32 1.07 0.1417 1.25 1.1 0.1475 1.18 1.15 0.1456 1.12 1.2 0.1368 1.08 1.26 0.1218 1.05 1.33 0.1102 1.03 1.37 0.0943 1.02 1.42 0.0000 1 1.67 E G /x1x2RT E 0.6151 0.6085 0.6382 0.6381 0.6061 0.6025 0.5834 0.5533 0.5441 0.5246 ln(g1) 0.6669 0.4244 0.3675 0.2770 0.2202 0.1617 0.1116 0.0747 0.0463 0.0331 0.0209 0.0000 ln(g2) 0.0000 0.0219 0.0355 0.0673 0.0960 0.1361 0.1836 0.2317 0.2826 0.3138 0.3506 0.5102 P(kPa) 20.01 38.65 42.52 48.57 52.45 56.74 60.94 64.68 68.34 70.5 73.01 83.99 y1 0 0.56 0.62 0.69 0.73 0.78 0.81 0.85 0.88 0.89 0.91 1 s 90.0000 80.0000 olumn G olumn H olumn I olumn J inear Regression or Column J olumn L olumn M olumn N 70.0000 60.0000 50.0000 P (kPa) 40.0000 30.0000 20.0000 10.0000 0.0000 0.0000 P­x1,y1 (experimental & calcula 0.1000 0.2000 0.3000 0.4000 0.5000 x1,y1 0.6000 0.7000 20.0000 10.0000 0.0000 0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 x1,y1 0.6000 0.7000 ntal & calculated) Column Q Column Q Column B Column B 00 0.6000 0.7000 0.8000 0.9000 1.0000 00 0.6000 0.7000 0.8000 0.9000 1.0000 MeOH(1) H2O(2) Antoine coefficints & Psat at given T T (d C) A B C 60 16.58 3638.27 239.5 60 16.39 3885.7 230.17 Pst(kPa) 83.99 20.01 Van Laar coefficients A12 A21 P (kPa) 19.9530 39.2230 42.9840 48.8520 52.7840 56.6520 60.6140 63.9980 67.9240 70.2290 72.8320 84.5620 x1 0.0000 0.1686 0.2167 0.3039 0.3681 0.4461 0.5282 0.6044 0.6804 0.7255 0.7776 1.0000 y1 0.0000 0.5714 0.6268 0.6943 0.7345 0.7742 0.8085 0.8383 0.8733 0.8922 0.9141 1.0000 Experimental values gamma1 gamma2 ln(g1) 0.9973 1.5827 1.0106 0.4591 1.4803 1.0236 0.3923 1.3288 1.0723 0.2843 1.2540 1.1085 0.2264 1.1706 1.1543 0.1575 1.1047 1.2297 0.0995 1.0569 1.3075 0.0553 1.0380 1.3459 0.0373 1.0283 1.3785 0.0279 1.0194 1.4060 0.0192 1.0068 0.0068 ln(g2) ­0.0027 0.0106 0.0233 0.0698 0.1030 0.1435 0.2068 0.2681 0.2971 0.3210 0.3408 GE/RT ­0.0027 0.0862 0.1033 0.1350 0.1484 0.1498 0.1501 0.1395 0.1203 0.1084 0.0907 0.0068 Experimental data & calculated values 2.5000 2.0000 f(x) = 0.47x + 1.47 R² = 0.75 1.5000 Column G Column H Column I Column J Linear Regression for Column J Column L Column M Column N 1.0000 0.5000 0.0000 -0.5000 0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 0.0000 -0.5000 0.0000 0.2000 0.4000 x1,y1 0.6000 0.8000 1.0000 an Laar coefficients 0.68 0.52 slope intercept 0.47 1.47 G /x1x2RT E 1.6258 1.6434 1.5669 1.5673 1.6499 1.6599 1.7141 1.8073 1.8379 1.9064 ln(g1) 0.6787 0.4229 0.3647 0.2737 0.2174 0.1599 0.1109 0.0749 0.0470 0.0338 0.0216 0.0000 ln(g2) 0.0000 0.0229 0.0367 0.0687 0.0971 0.1365 0.1830 0.2300 0.2801 0.3111 0.3480 0.5157 Calculated values G /RT gamma1 gamma2 0.0000 1.97 1 0.0903 1.53 1.02 0.1078 1.44 1.04 0.1310 1.31 1.07 0.1414 1.24 1.1 0.1470 1.17 1.15 0.1449 1.12 1.2 0.1362 1.08 1.26 0.1215 1.05 1.32 0.1099 1.03 1.36 0.0942 1.02 1.42 0.0000 1 1.67 E P(kPa) 20.01 38.63 42.47 48.48 52.36 56.67 60.9 64.67 68.35 70.53 73.04 83.99 y1 0 0.56 0.62 0.69 0.73 0.78 0.81 0.85 0.88 0.89 0.91 1 s 90.0000 P­x1,y1 (experimental & calcula 80.0000 70.0000 olumn G olumn H olumn I olumn J inear Regression or Column J olumn L olumn M olumn N 60.0000 50.0000 P (kPa) 40.0000 30.0000 20.0000 10.0000 0.0000 0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 20.0000 10.0000 0.0000 0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 x1,y1 0.6000 0.7000 ntal & calculated) Column Q Column Q Column B Column B 00 0.6000 0.7000 0.8000 0.9000 1.0000 00 0.6000 0.7000 0.8000 0.9000 1.0000 ...
View Full Document

This note was uploaded on 02/23/2011 for the course CHEM 1030 taught by Professor Staff during the Spring '08 term at Wyoming.

Ask a homework question - tutors are online