web1 - CHEM 313: Inorganic Structure and Bonding II (Holger...

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1 CHEM 313: Inorganic Structure and Bonding II (Holger Kleinke) Prerequisite: CHEM 212 Textbooks. Housecroft, Sharpe, Inorganic Chemistry , 2007; Miessler, Tarr, Inorganic Chemistry , 2004; Huhee Keite Keite Inorganic Chemistry 1993 Huheey, Keiter, Keiter, Inorganic Chemistry, 1993; West, Basic Solid State Chemistry , 1999. Lectures. Tuesday and Thursday, 10:00 - 11:20, PHY 313. Office hours. Wednesday, 9:00 - 10:00 a.m., C2-067. Evaluation. Assignments (10%), one 75 minute mid-term evaluation (30% each), one 2.5 hour final (60%). Class home page: http://kleinke.uwaterloo.ca/313 Backup: http://www.science.uwaterloo.ca/~kleinke/313 1 CHEM 313: Inorganic Structure and Bonding II (Holger Kleinke) Prerequisite: CHEM 212 CHEM 212 Atoms, orbitals, and periodicity Geometric structure and localized bonding models Symmetry and group theory Valence Bond and Molecular Orbital theory 2
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2 Lewis A Lewis acid is an electron pair acceptor Acid/Base concepts and different solvents A Lewis is an electron pair acceptor. Lewis base is an electron pair donor. The Global Definition: - incorporates all of the above ideas - and provides a criterion for relating acid/base properties to electronic structure structure. Acidity: The positive character of a species that is decreased by a reaction with a base. Basicity: The negative character of a species that is decreased by a reaction with an acid. 3 Proton Transfer Equilibria in Water Conjugate Acids and Bases HSO 4 - (aq) + OH - (aq) H 2 O(l) + SO 4 2- (aq) acid base conjugate acid conjugate base PO 4 3- (aq) + H 2 O(l) HPO 4 2- (aq) + OH - (aq) acid base conjugate acid conjugate base 4
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3 Strong and Weak Acids and Bases 5 Strong and Weak Acids and Bases 6
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web1 - CHEM 313: Inorganic Structure and Bonding II (Holger...

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