cycloalkanes-cont

cycloalkanes-cont - 2 group Boats, bicycles, fused rings,...

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1 Alkanes-continued Fig. 3.13 Axial and Equatorial positions
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2 Page 123 Eqn. 1 Page 123 Eqn. 2 Page 121 Eqn. 1 Page 122 Eqn. 1 Page 122 Eqn. 2
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3 Measuring Strain •Heats of formation •Heats of combustion Heats of Combustion Heats of formation for Cycloalkanes Column 1 observed Hf°; column 2: Hf° per CH 2 group Column 3 is the strain-free H f °(-29.4 is strain free for 6 carbons); column 4 is the difference between column 1 and 3; column 5 is strain per CH
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Unformatted text preview: 2 group Boats, bicycles, fused rings, and spiranes Fig. 3.14 Rotated 90 4 Page 127 Eqn. 1 Page 127 Eqn. 2 Page 128 Eqn. 1 Tables on your exams: 3.8 CH 3-CH 3 gauche 11.0 CH 3-CH 3 eclipsed 6.0 H-CH 3 eclipsed 4.0 H-H eclipsed Energy Cost kJ/mol Interaction 5 1,3 Diaxial Interactions 0.4-CN 2.9-COOH 6.3-C 6 H 6 11.4-C(CH 3 ) 3 4.6-CH(CH 3 ) 2 4.0-CH 2 CH 3 3.8-CH 3 2.1-OH 1.0-Br 1.0-Cl 0.5-F kJ/mol Y Y H 1 2 3...
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This note was uploaded on 03/01/2011 for the course CHEM 030.205 taught by Professor Klein during the Fall '09 term at Johns Hopkins.

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cycloalkanes-cont - 2 group Boats, bicycles, fused rings,...

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