questions6_fa10_ans

questions6_fa10_ans - Chemistry 030-205-01 October 14, 2010...

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Chemistry 030-205-01 October 14, 2010 Problem Set 6 1. Complete the following reaction and describe the stereochemical relationship of the products. -H product H 2 O intermediate Br 2 Br Both bromonium ions form so you get R+S isomers at the asymmetric center. 2. Which of the following molecules is/are chiral? Cl Br Br HH A OH OH B H HO HC O O H OH COOH C A and B are chiral; C has a plane of symmetry 3. Which of the following molecules is chiral? CH 3 CH 2 CH 3 Cl Br 4 . Circle the stereogenic centers in the following molecule: O Nootkatone (grapefruit oil) Nootkatone (grapefruit oil) O
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5. Which of the following cyclohexanes is (are) chiral? The 2 nd and 3 rd are chiral as they lack a plane of symmetry. Assign absolute configuration in any that are chiral. R a stereocenter but its absolute configuration cannot be assigned S
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questions6_fa10_ans - Chemistry 030-205-01 October 14, 2010...

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