questions8_fa10_ans

questions8_fa10_ans - Chemistry 030-205-01 November 4, 2010...

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Chemistry 030-205-01 November 4, 2010 Problem Set 8 1. Provide possible starting materials for the following reaction: ? 1) O 3 2) Zn/H + + O H H H O O H O H or 2. What reagents would you use to complete these reactions? O O HgSO 4 H 2 SO 4 /H 2 O several steps O 1) NaNH 2 /NH 3 2) CH 3 CH 2 Br HgSO 4 H 2 SO 4 /H 2 O
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3. An unknown hydrocarbon A , with formula C 6 H 12 , reacts with 1 molar equivalent of H 2 over a Pd catalyst. Hydrocarbon A also reacts with OsO 4 to give a diol, B . When oxidized with O 3 /H 2 O 2 /HOAc, A gives 2 fragments. One fragment is propanoic acid, CH 3 CH 2 COOH, and the other is a ketone, C . What is the structure of A ? What is the structure of
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This note was uploaded on 03/01/2011 for the course CHEM 030.205 taught by Professor Klein during the Fall '09 term at Johns Hopkins.

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questions8_fa10_ans - Chemistry 030-205-01 November 4, 2010...

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