CHEM2090-LECT13 - ~ ~ p hase(501 o u.n:Lrrr s A ~ ma-er;A ~ ~ ~ i d c j a ~ ~ condensed phase.^ everythin3 hat;s n d.gas a I 1 n e11~,rno

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. . . ~ ........ ...... . ~ ....... - ..... - .... -. . . phase -. o, u.n;:Lrrr, .s+A+~ ma++-er (501 ;A,. . ~~~.id. .+.cja~~-. .. . - ... -- . condensed phase-. .^- everythin3 +hat. .;s. nd. a .gas. - .-- -. I \ 11 -. 1 .n f.e~ ,rno I~ec -&.me s ._ - _are. .-b eheen mo.1.e~~. 1e.s.~. - - - I\ I r ......... -.. .- Sntrcx ~nolecolar &CC~S.- arc. ~ith;.n~._arno.letcele. ................................... ........... ............ . . . . . . . . . . Lrces am: $.,+armok"J(hC -.~ I . . - .kv ndcx-m.en+ar\~y. doni.na+d by Co~~omb;c.,Crc.e . . ....-. .. . o( 9\91 .-. ............... - - F -. . (> f . Dipole rn-~m-enf F. p .-c7 -- . . ....................................... - ue So oneven ..................................... . . A ;S+.P;bu~M .o.~- ..................... f. .Lono\on oc D;spersion -Forces: -- -- - - - - - Induced ~iiole ~ndored-d;pcle - Iar er atoms are more poklcrk&,le leeare less SigMly bovn~P) f9 ne+ ~++~+;ve-be-.ure & + d shrinks a', E? , bof -
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. .,. .,rJ need .to ion - dipoie -M * 4& Y ~qvad isbne -CCC ...-.-. .. -. ....-. .... - ............... ....... . ....................... d;.pole.-.d; pole. ... . . . . . . . . . - ...... . - . .- pocctiall . CD va1en.t - ..... Y \ #t .-. . . .................... +\?bt cc4n~b.e. +ho.oght o~. . 3~-.ren.+e~ bnds - ............ .need : H . b~.w nd . .+u. an el .ec.troneqaf;~e. - " 3- r entered bodf' pmhn skbc~\;zes -the negahX c)aTle o$ bh abm~ and polls them +~~e+-her, e- are shape/ by al\ 3 atoms
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. . . .... ~--im.p~.bnt .-&r.--pack; n and rno lecvlar .W~M ernenls : --. - ..... .. 4 9 ..... ...... .- . ....... -........... - ....--. .......... . Y ...... .-.due b d.ic_ec.kbos.S ;+ 0.S. H..-.bandd;ng -- -- !, .
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drI7si-+y l pui~d away qmm @ meltin 9 po.i,?t, hoi\i 3 ~bil7t - Ae el-, 5 or, ~4'- iniePaction~ P d lhyc\rclcen 3 -bor>di,?cj, dipoie -dipale. .
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This note was uploaded on 03/01/2011 for the course CHEM 2090 taught by Professor Zax,d during the Winter '07 term at Cornell University (Engineering School).

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CHEM2090-LECT13 - ~ ~ p hase(501 o u.n:Lrrr s A ~ ma-er;A ~ ~ ~ i d c j a ~ ~ condensed phase.^ everythin3 hat;s n d.gas a I 1 n e11~,rno

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