Problem Set #12 Substitution and Elimination II

Problem Set #12 Substitution and Elimination II - reaction...

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CH 3 CH 2 Cl + Na OCH 3 C CH 3 CH 3 CH 3 Cl + Na OCH 3 1-bromopropane KCN i-Pr-Cl OH / H 2 O room temp i-Pr-Cl KOH / alcohol heat CH 3 -CH 2 -I Li (n-Pr-) 2 Cu CH 3 -CH 2 Br Li° CH 3 OH CH 3 -CH 2 Br Li° CuBr CH 3 I EtCl Mg Ether EtOH CH 2 =CHBr Na OCH 3 I KCN Organic Chemistry I Problem Set 12 Substitution and Elimination Reactions Complete the reactions by drawing structures of major products. Indicate important minor products. If no reaction occurs, write NR after the arrow. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11.
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Answer the following questions: 1. Optically pure (S)-3-bromo-3-methylhexane is treated with water and a substitution
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Unformatted text preview: reaction forms an alcohol. Write the structure of the alcohol and describe the stereochemistry of the product. 2. (S)-2-chlorobutane is allowed to react with NaI in a polar aprotic solvent, to yield a substitution product. Write the structure of the product and describe the stereochemistry of the product. 3. Use equations to describe the mechanism for the reaction of ethyl bromide with potassium cyanide in acetone solution....
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This note was uploaded on 03/14/2011 for the course CHEM 238 taught by Professor Raucher during the Spring '04 term at University of Washington.

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Problem Set #12 Substitution and Elimination II - reaction...

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