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MT2Au07blank - Copy - Callam Chemistry 251 Autumn 2007...

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Callam Chemistry 251 Autumn 2007 Page 1/12 Midterm #2 200 points Name (PRINT)_____________________________ I have neither given or received aid on this exam (SIGN)______________________________ Place an X in the box to the left of your recitation section. Failure to mark your correct recitation section will result in –5 points from your exam total. T 1:30 p.m.-2:18 p.m. Matt DeMatteo R 1:30 p.m.-2:18 p.m. Matt DeMatteo T 1:30 p.m.-2:18 p.m. Chad Eichman R 1:30 p.m.-2:18 p.m. Chad Eichman T 1:30 p.m.-2:18 p.m. Nicolas Proust R 1:30 p.m.-2:18 p.m. Nicolas Proust T 2:30 p.m.-3:18 p.m. Matt DeMatteo R 2:30 p.m.-3:18 p.m Matt DeMatteo T 2:30 p.m.-3:18 p.m. Chad Eichman R 2:30 p.m.-3:18 p.m. Chad Eichman T 2:30 p.m.-3:18 p.m Nicolas Proust R 2:30 p.m.-3:18 p.m. Nicolas Proust Part Points Score 1 18 2 11 3 24 4 25 5 12 6 20 7 40 8 34 9 16 EC 6 TOTAL 200 Please read all of the directions for each section of the exam carefully. There are 12 pages including this cover page for Midterm #2, please check to make sure you have all of the pages. Make sure your answers are clear. Any structures or answers that are unclear or ambiguous are considered wrong.
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Callam Chemistry 251 Autumn 2007 Page 2/12 Part 1. Nomenclature and Ranking. a) Provide the IUPAC names for the following molecules. (3 points) b) Provide the structures of the following molecules based on the IUPAC names given. (3 points each) bicyclo[2.2.2]octane (R)-2-bromo-butane c) Rank the following alkyl halides in order of increasing SN 2 reactivity. (1 – least reactive, 3 – most reactive) (3 points) Cl Cl Cl d) Rank the following alkyl halides in order of increasing SN 1 reactivity. (1 – least reactive, 3 – most reactive) (3 points) Cl Cl Cl e) Rank the following alkenes in order of increasing stability. (1 – least reactive, 3 – most reactive) (3 points)
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