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Ch8-Note - Cfla CE) GE‘riui-k :W: v—fiir CM 4% + ~ A...

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Unformatted text preview: Cfla CE) GE‘riui-k :W: v—fiir CM 4% + ~ A m flow? ‘3 _ 3 Ajcutfi") vi #3ng + CH (G33 REF = 2xm'”° 1A5] : LL, x104 (Haiti: AJCNH) dis-5M “CH ) Mm,.flp}m 51M muswfm) in brinj m Wm :hs Mrs. m [135'] Mam} 3h: LQMD-E — QBGZ, LEM/«3,6 TM,1JM ' goth m in Wfiu " fifiu A5! we- ‘ Kon‘xcfflcrt 3% 1‘ {3-3} lunic Strength = P- = 3 EC: 2? :' Cj, :- CDncafim-Hun 4? .101 i Z: = Liking; an inn 1". m4 HMO} Jr: aflr 0.10 mm} H“ ‘ND: fl : 13({n.1n+‘)[+':)1+ (OHM-1)") = 0.10 “1 FM :1 1311,41 W} /£(= CanCEH‘lraJti-DH C hem3flfl ChupIEr Fl Lecture Nuters page 2 Cami/ML mm W Camuga «it 0.13m (Fiji. 2ND:- /a= fiflmtuflfl): + mam-01) = 0.35 m M, Agar-a) mum-gm W magi, 5/3 MAM cg 0.1 w 1mm} (lawn) liumwmmflmifld? Th . ‘ ' m (Jug/1.2m 5th (has;ka mrfiuér Elma-ll- in 311L521 :1 wag +13; {m wu W M 1:43;: m M {a} jwjfifl-fl.ln 0.1%) Thug, M W m WM Wflfmodgpnam‘m §ormali5m {QCDJMMEW GHDWLidE gu‘luhm" bghfiuim" ‘0 Dltéjmmfj QCinuHias a mi“ 5W. WM] gar A H5 :3- C +53} aaxhadriuffl/d u<= amt, = m: [b1 51 m- :11an LAM may; waif {c} rd: . W » (1M ' £09321;an m‘m fl EE—BriMani‘aH rflximafkflo' ‘0? Lawmfimfi‘a fififigmwwa Chenfiflfl Chapter 3 Lecture Nntes page 3 him Jam, CH4. {ti-6] Extended Debate-Hittite] equatifln 43.5122wa t, _ . _ . I - —-~—-—~ at 25 C] 'f— actmty sscffieient 0“ 1+{aaXu/3fl5} { Mime Mia +3; diamslsr :3 HQ Eadrflwl him use incl) rat-v1 and table 1.0 {in pay HO?! Big]; .5: 0.8 TM} yq . W E W 9"“ -5i2s(h W) git-'5 - mm: is Eaafix vain V gimme: I” amt 11m} {in in Tahfi w W W Bani-t: strength {a '—"'_'_"_ Figure 8-4. Activity soafficisntsfnr differsan M 5L charged ians with a‘eaastant hydrate-d diameter £191 0. W J. 3:33:32:fissiisisiitsgss Wt wt 15% «If it decreases as ionic strength increases. Nate g‘l in, w T that the abscissa is logarithmic. [W "l’QQ/M 5mm {bag um gas. Mam) loaLQa is can Haiti‘s) ' 0.10 m mo ) [At] 51,2013“! Hm ‘5 1]: with?-% (:5de W —‘1‘ C4. + Cli*+C[H“+ CNfl_ = J“ '1( Baler? [Lie In”? 040;) HUNTEI'OIE 8-1 Xi he; = 0.1570 @fl=0.to X“; = 0.355: [9!“ =D.m Chem3flfl Chapter 3 Lecture Holes page 4 Hal“ = Cuff OW = [Aglllimflbfifflw = QKlO—H” X K {fiJI/1: X = Li, my? WI 0W mmWfi/{WM Mia/Qummfixmg’a F33 0 in Figure 3-3. Solubility of potassium hydrogen tartrate increases when M9304 er NaCl is added. There is no effect when glucose {neutral} is added. Additien ef KCI decreases the seiuhility. {whys} {1.432 Petassium tartrate seiubiliry {M} e: c: E E a 53 D d 8 . —-—I—.—L_I_I_L_i DUB GD? 1154 QUE 1193 0.11} Cu neentratien of added substanceer 3:25 media er/a-dmm 2H ELM/35 <2 LG E 1.5 (m WW s3) Ere disssiusd all . DIED 1i 2 1 W1 3 i J i1 {M} x“ (N 91 ) Figure 8-5. Activity eeaffieient ef H' in seiuti'ens X W W Qfg eentaining [Ifl‘ififl M HDIDa and varying ameunts '5‘— Fisww 9V5 fhemi’rflfl Chapter 3 Lecture Holes page _ Hem aka$ CLHJVDPr¢+d3Si£ Cg MIR? Gila [Adm [H+][OH'] = Lm x; [SCH @ 26L # .i. [H+] = [OH‘] = Lagg- NEE"? m MW flu; Wig in”; fur/a :19; M 3/:1 [1.1+ = [H+] and aoH- = [OH—1 {OH = 49133 am = (7.06 Nfiihgfi’; 8% i6 fl=-0.l0 IE Now, {at @3? mm flu: m. Nu: = (ll-H Qm‘ = [H+][OH_] XH+XUW fir = [H+][OH‘] FmTafle £4 fi+ = 0.23 @ (Ll/u 340.4- = 0.2:; @ Cal/u [H1 —1.:?£, Nagy] (=[QH'D PH = —Q1gOH+ = —%(L2£X¥B‘TK 0.33) 7? = mg NOTE. gris— Chcmfiflfl Chapter 3 Lcaturc Nutcz; page E- Tfii Comma Eon Eiltgflfjf Coman’rmjcim .553 im BAD i211 Natl H10 ' A305) : Ag + CF K=I.3K10“m 2'5"; 3 w, M mn- 4AM Mu :0 L [R5*:[=[C1‘1/M= LSfiND-‘S—m Ham _‘ Aug; w or J imjriafl Emmi c? om; Fahd $n‘xid... ‘34 040 Jr E“: (ii 0.10 H1 “flaw = [LID {Igg- = 0.35 ya.- = 0.?55“ Salty F____ : (3"?) Dim) 4-K) a" C" W X {vi fl-lO Luna“ 1. (x)(0.m) 1 X: 3.19, X103 m [0.215) (0393:) g [gnarllfiJ‘B/k) LBKID—q N802: ChEmSm-j Chaptfir F". Lecture NUIEH Pal-“3 7 9+Em¢+icmfi+m E uiibrium Saloflom we. diagokuz: Marga Jm HA3 13 .0; gofdfm Lama—3m 4w HCI. MCI HAD Hung) 3: Cir-£1) bah 2WD a: H50++~ of Or] Wm. Complicate») Shppm Lee AMEN Hufflq 3h; 0.! F Md mu :H/u HJEHJPG ~1,EHPO 1‘] (PH 3’? mi WM? P H H " q Riflwnflt Bguli brim WU: k :41 Pm! :2 [W + H; Poq‘ Hid/i: HAPOH'JF mo .—.,—_-*=~_~ {435504 + 0n- !JJPOLF + H5 :2; 1450* + H mf— HPOJ + My :2: H$0++ 690$“ Make) MAD-:3 Hgowflv L'henfiflfl Chapter H Lecture Nntes page How City [136 tut"de Mom! 61 WW? (me 8 dumb a Wham-E WM. —TmJ{BJ. HHAPQH wafigl turf; Mi: 7 Lbkgmk‘m 3- 14*, w] 16, Hpmq, HAP-“3;, HPmfi‘, PM Z Ton-5G3 1* Z IUHLC_) L19} W @491 M C'Gfigiclléfl [W] + [m] : [HAPofi + éfllpéq1‘1+=:i[PG,F‘34 [Eur] 056.10qu whining (Ham-q; HM) {EMF} Exit} TEA Lb: Canal?” :11 f; Chenfiflfl Chapter H. Lecture, Nfltfifi page E} 1.1 mm’fmamga aim fi¥M if; mafiqfimw Mam _ {HHJEJSMIAQJ fHémfl’r EHLPofl +f14toasf‘} [Mi : [161 a. 531% “r M W NOLA. imdiQEmMCfi%@ GLCf-iuifigg CUhEcahi qu1 ion; €+W 316136991 WE diaeouwh “QUE—JUL] L130; Hal-150;; ———==* Hus;3+ + 1430.1." {ea/é H90; + lilo r: $qu 4 OH‘ 14230; + m :3 90;?“ + use? and 21—13. :3- Hfi + cur image W: {HELENE : EHsmfl + flaw? + [UH Mam EDQQIMLE [Nail : i’ILquI+KI-rsaq‘14 [SM—1 ChemEflfl {hapler 3 Lecture Notes page If! H um r. [14‘ [NH] [uni W M 9 {Hi-in, ham]: [gar] : é EszCl-Hmn; I a, {an 9am in ErimriElE S+Ep~3 ‘hs wp (Luiw'miwg flu (Draw: {[3 Mme germane PeacJEiong (33 wnxh flu c/[na-véie @Iéuritim N? (3 mm“: mam BaQam afiuétzm (Whigs 0” L45; Camuth {aefiicigm m if M) ('3) 80M: +5» flu. Sfilulflflh m jag/LL L1an paflL_ LJ- - t ( w W) USE. aflfiflammwahfing magma:— (ixgg‘allafli T __ Chen-GUI] Chapter 3 Lecture Hutcs page I 1 Q)qu h {Holdup = to MUTE '3: CD HCl fla- Hjo++09 mi 2 HA) $ 1433043; can" wmw MW [1156*] = [OH] + YOU—7 (3) Was; [Ct-1 -= m"? (H) mud; Efflibrium Cow;+mdb Rm :3- Dwfliofl = 10"” (9:) 801%: J? Emm mama) ECI‘I = [143m] -{ bufl : I0 .1 [0H‘] = [Hag-flhm-E ¥rm0s§ 10-!” = [W] (L1H 45-31) 2 [WE — 113*“ [14* 0 t [W- — |U“9{H+] 40"” Sum o=ax1+b><+c PM 6% C hamml} Chuptfir 3 Lfictun: NUIE-‘fi AWE-HUI Exam & page I E Soiuloililry :93 A510.) Jim 0.1 W1 aqjurzms. .flmmawm Ulnd Gm flaw tibia; Li R611) 4. 1;;qu Mar, (36% Mil; W A5 + m5 ——“__;==- flag—M143 Ki ASHNHE + H1413 E1“- HH; A3‘HH3 K1 cam M. W owl firng (my. L.) Hui :34 km M 0w: abbuli'art'm NH: + mo : Hug} + ou’ m, For cumplm‘emw, L”; W 19“; 21410 # 14bo++ W“ Th “had: thulilor'la m: [D Nap = 9'3 HF” = [AgilEIi—ZI C23 K; = marl/mgmm = 9.04m; (3) K: = [113:2] / [RSLJ'HNHQ = 3.15m?- L'hemiflfl Chapter 3 Lecture Nutes page 13 (“0 Kb: 1.?3 5:105 = [Hl4flfolrj [N145] (55 RN: EIJ’QEDH] : 1.00 MCI—1“ Uanomnaz Diff], Half}! [133$], [1'1 WHJ, mm; [ml-1 [My]; 8 WW; UL W Mme. Egbua‘h‘ana: mmm Emu (1mm 93am (<23 [1-] = [A5] +£A3L+1+EA3L31 [9) [anfl 3 0.10 = man {My [##3er SEASLEJ Charge, balance. — (g) [131+ [014-] : [Hflqummgfl +IA561+LA5L21 Hum! $01.33— SM ‘ iii-am. (IQ/miaa ' W ELMO; W —- “Ham Emmm FHA/1W GM] [0M ?7[Hr_[ L'hemiflfl Chapter 3 Lecture NMES page I4 - Campbmjlm mna’tda N. I Ham W W J M Afr in ' ' mmAam will hmflu§fim a? [Abhfl 1.13.; fly: I'QIKI : {Hug—l; : LIL; LuLuAL [AS-1 ‘1‘“: {RbL‘q {‘74 LAbLfl ern. Mmbulamte [1-] 2 Wm —'1'(¢P .54: *0 mam Mfg; in” l q M amplexmm aha; MT W R5133 a " .0616 M raw,” 0%; MW, flaw Wirggmm 13+E+1+inuq1= E: wan—:1 LIE—,4) W ‘ n r WV *5 a E m cm! [Milli]; [aw—J T Hall fi-L [PM P“ It?) W17; EQFJIDUTEJ wfl} NH; |~21u Qfiuhbaum mafia, Sc} Rb: mafia: [NHflEOH‘I = (K300 [NHgfl (DJ-44“) DI" K14 135 mfg $1 43$” Ilia—t" :- D Quadrflk 4m... 3L: 1.31.1 “0‘3 : [Nufl=[afl C hemiflfl Chapter 3 Lecture Mules page 15 mug] = {mu—x = 6.0%,, 2 0.10 [PEEP] — Um} way/9);: 5111-] [A33ng =1.u.m’*xg.gm'” [TE—12 [A33 [HIng = L33 Elm—q : [HHS]; {gr—j 4: DU ~ = , 0 EHHfl 371M ._ K.» (3.0012; CML: ax mg] w my] 4: CASH] ,7 Nip = [MELT] = 3.3 we"? EA3+1[3.M. MO“) = " [AS]: 2.3 we?” <4 aflmtfé' V KI = Qifixlflg _ Li] Digit H1433 tame" )(ome) [ASE] = Hfixmfi <4: 3.“? Km"; 1/ (§&e%nra$%11) film} [AM] a: [um :21/ 3,? new 4:" 0. M3,; Wfiffld NH?) : {Ll Km"Cr [ASLf—j “HE = (5,? Xm‘t’ “Mari Chcmfiflfi Chapter El Lecture Hutcs page If: :19“ Equlibria as a Function of [I'] x. ,..._,..«-""![A'CJ] _.-' Total Soluble Log [cone] Lug [con-3.] [AngHg 321+ AngH3JJ+ .15 [figzlfi]4' 4-3 -9 -a 4' --5 -5 -4 -3 J —1 a [#993]? ...
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Ch8-Note - Cfla CE) GE‘riui-k :W: v—fiir CM 4% + ~ A...

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