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handout 7 - methyl –CH 3 3.6 ethyl-CH 2 CH 3 4.0...

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Handout 7 Strain in Simple Alkanes 3.1-3.3 Interaction Type of Strain Energy (kJ/mol) C-H, C-H eclipsed Torsional 4 C-CH3, C-H eclipsed Torsional 5 C-CH3, C-CH3 eclipsed Torsional, Steric 17 CH3, CH3 gauche Steric 3.3 Strain in Axially-substituted Cyclohexane 3.10-3.12 Substituent Steric Strain Caused by 1,3-Diaxial Interactions with an Axial H (kJ/mol)
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Unformatted text preview: methyl –CH 3 3.6 ethyl -CH 2 CH 3 4.0 isopropyl -CH(CH 3 ) 2 4.3 t-butyl -C(CH 3 ) 3 11.4 -CO 2 H 2.9 hydroxy -OH 2.1 bromo –Br 1.0 chloro -Cl 1.0 fluoro -F 0.5 cyano -CN 0.4 Chair Cyclohexane, Color-coded to Indicate Bonds that are Parallel 3.7-3.8 ax eq eq ax ax eq ax eq eq ax ax eq ax eq eq ax ax eq ax eq eq ax ax eq...
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handout 7 - methyl –CH 3 3.6 ethyl-CH 2 CH 3 4.0...

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