Quiz 2 - 3 O Br Cl CH 3 O O 2 N O 2 N 3. (2 pts) Write the...

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MCMP 205 Wednesday, February 4, 2009 20 pts Name __________________________ Lab TA _________________________ Lab Period ______________________ Quiz 2 Page 1 1. (2 pts) Write the number 1 below the compound that would react most rapidly in an S N 1 solvolysis reaction in water,acetone. Write the number 2 under the compound that would react second most rapidly. Br Br Br 2. (2 pts) Write the number 1 below the compound that would react most rapidly in an S N 2 reaction with NaI. Write the number 2 under the compound that would react second most rapidly. Cl Cl Cl 4. (4 pts) Write a stepwise reaction mechanism for the following transformation. Use the curved arrow notation to show each step in the reaction but you do not need to show resonance structures. N F N OCH 3 NaOCH 3 HOCH 3 CH 3 O CH
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Unformatted text preview: 3 O Br Cl CH 3 O O 2 N O 2 N 3. (2 pts) Write the number 1 below the compound that would react most rapidly on electrophilic aromatic substitution by HNO 3 and H 2 SO 4. Write the number 4 below the compound tha would react most slowly. CO 2 H F CH 3 OCH 3 1 1 1 2 2 4 N F O 2 N OCH 3 N F O 2 N OCH 3 NaF 2 pts 2 pts Page 2 Name _______________________ CH 3 O OH 5. (5 pts) Fill in the reagents needed to accomplish each of the following transformations. a. b. Br CH 3 Cl Br Intermediate Intermediate 6. (5 pts) Fill in the intermediates in the following reaction mechansim. OPP H 2 O OH OH 2 OPP KMnO 4 or NaCr 2 O 7 , H + FeCl 3 , Cl 2 FeBr 3 ,Br 2 NBS or Br 2 free radical initiator 1 pt 2 pts 1 pt 1,2-hydride shift 1 pt 1 pt 1 pt 1 pt 1 pt for correct order either order acceptable 1 pt...
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This note was uploaded on 03/30/2011 for the course MCMP 205 taught by Professor Staff during the Spring '08 term at Purdue.

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Quiz 2 - 3 O Br Cl CH 3 O O 2 N O 2 N 3. (2 pts) Write the...

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