Errata_SGSM5E

Errata_SGSM5E - Study Guide and Solutions Manual, Fifth...

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E RRATA Study Guide and Solutions Manual, Fifth Edition by Marc Loudon and Joseph G. Stowell to accompany Organic Chemistry, 5th Edition, by Marc Loudon Date of this release: April 2, 2010 Items marked with an asterisk (*) were corrected in the second printing. Chapter 1 p. 2 In the second line from the bottom, the expression should be 4.8 ± 10 –10 , not 4.8 ÷ 10 –10 . p. 12 In the solution to Problem 1.32(a), in the 6th line, the reduction in % s character should be 2.3% in both places. That is, 25% – 2.2% should read “25% – 2.3%.” Chapter 2 p. 17 In the first display, the condensed formula for isopentane should have two, not three, methyl groups. It should be (CH 3 ) 2 CHCH 2 CH 3 . p. 20 In Problem 2.10(a), one carbon has two labels. The correct label should be t . The correct structure is p. 21 The name in the solution to Problem 2.13(a) has incorrect numbers. The name should be 1,1,2,4- tetraethyl-3-methylcyclobutane. p. 23 In Problem 2.32(a), the substituent name “dimethyl” should be cited before “propyl.” Chapter 3 p. 36 Although the solution to the problem is correct, there are two errors leading up to it. First, the initial equation is wrong (font errors by the compositor): K eq = 10 ² G °/2.30 RT = 10 –(–2.93)/5.71 = 10 0.513 = 3.26 Then, in the second equation below the table, there is a superfluous “=” sign and a minor numerical error; the equation should read x 2 ± 0.607 x + 0.02 = 0 The correct quadratic expression and the solution follow from this.
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Fifth Edition Text Errata, April 2, 2010, p. 2 Chapter 4 p. 57 In the solution to Problem 4.13(a), the ± value 4.06 kcal mol –1 should be negative. p. 67 In the mechanism at the top of the page, the product of step (a) should have two Hs on carbon-5; that is, the H that was added in this step was inadvertently omitted. Chapter 5 p. 85 In the solution to Problem 5.2(c), the solution to Problem 5.2(b) was given instead. The correct solution is p. 89 In the first structure of the solution to Problem 5.22(a), the unpaired electron dot is missing. The display should be p. 90 In Problem 5.32(a), on the last line at the bottom of the page, the alkene is incorrectly named. It
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Errata_SGSM5E - Study Guide and Solutions Manual, Fifth...

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