HWQ-Chap-7-3530 (1)

HWQ-Chap-7-3530 (1) - CH4 . "Fe Hm fiwé‘m e at...

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Unformatted text preview: CH4 . "Fe Hm fiwé‘m e at the meet extmlsivei'e studied reeetlnne D‘ lustr'tel ehemietnr is the swthesis ef er'riireenier es its eueeessmt eneretten hetps 1e Ewan the effleienee el tee entire eeeneme. The standard Eieies enere'.r ef fen-nation uf N'Hgllgi is —1E~t.5'le.l rnel'l st 2313 it. Whetiettte reeetien Eilehs anal-m.- whan the palatal preemnre let the N3. HI. and NH_ teeeted as perfect gesesi ere 3.1} bar. “LEI her. and 4t] leer. res;:ne-::t|-~.reI-«,ri II.I"I.I'het is the seenterre-eus direction ef the reeetiee in thIB eeee? he eeuiIitn-ium eenetsnt ter the reeetien e + E .—-‘.' :3 t‘, is repel-ted as 3.4 s tfl“. What weuei it he fer the reeetiee writteut '1?! la] 2 iii-i 2 Eur—‘46. {lei %A+%E r—‘C? @Thfl standfi'rd reeetien Gib-lee. energy- ei' litre i-sen'ierieetiren Sifl-E-F‘BFTHT'IH te Ilene-Eeettene at tic-D it is -r:EI_Ii:‘Fir hJ met"- Calculate the errmtihriurtt eensteet at the isrwneriaetiun. m The standard reeetien finesse—Edie + Hufllgl _+ Enfltei + lite} ie werettimetehlr meters at +231 hi met" here Q's-:1 it Ly m 1231] it. The steneerti reeetier: Gib-e5 emerge 53 +33 M reel" st 12% it. Assuming that herh quen- tinee remein eeretent. estimate the telnnerettee at when the eeuJimriurn eeheterlt been-thee Heater then '1. tht'jj Cemhine the resetien entreeies waisted in the fellew- ing reeetieee iehti'. the teeetien entheleies and seine-term the stander-:1 reeetien lGiletis energiee at 293 K. tel HCIiQfl-I- NHai-g] --+ HHHCIisi let 2 AIEDJIEF + e site 4 e Siege} + e ens:- eierhte the slenderd hietd-gieel Grebe energy fer the nine P‘p'l'lJ'I'Etfl' r NADH + H‘L —1r lactate + MAID" st 31D it e'reen that ere“ .1: .561? kJ met-i. [MD' .5 the endured term eI niereinernide dinLIelee-tidej this resetien eeeurs In muee‘re eelle deprived ef unseen during strenueus exercise end een Ieed 1e elem-e I 3.41m“ Er gas-[Erase ennui-Em mixture ef EbEIE'. Shfllm and I? at 530 lt. ,efibcia e H.15bersntt pm + 0.2:) bar. Calculate he eeuifibrium pertiet pressure ef ClE give": that He 3.5 :at1{l"‘1 fer true react-m Seth-let e! Sbfilgtgl + Clatgi. _—|.|—. . x“ ' . @ln the Haber preeees ler emmene, K = ilflflti fer the reectrerr Natg] + 3 HIIQI 7—“ E Nt-Igtgll tit EIIJU H. H e reecter is ehergee wrt‘h pertiet pressures et" E1020 be: ef MI and 0.41m? liter DI H3. whet I.-'|.-'i|| be the eeuilihn'rrrn peruel wee-ewe Dim murmurs? a 5?”- 5T2 Eensider the equilibrium. Nate] 1 3Hgig, -— Ethaig}. The value ef the equilibrium eenstent is HF- 33? at 100 it} and K: 7.1}:1U " e: EDI] :I: [e] Determine the errthelptr teH’] enel E'I'Itrflp‘j teS‘fi ehenges fer this reeelien [b] Determine the melee ef the equiltbrium cehstent at EDD “D. [c3 At EDD “'13. the initial pressures ibefere reeetien te term NHg] ef H: and H: are 1.4} bar err-e 3J3 bar, respectively. Calculate the pressures efell 3 gases at equilibrium [Mele: "r'eu een me he the assumptien the: very little NH: is fermee relative te the initrel pressures at Me. and H; 1e s:rn pl'rfg,.l [.Ieur calculatien]. id} Determine the lE-ibles ertergt.r change fer the reectier'. at 5th} “:1: fer PM: F'..; = 0.2 bar and Fe I; = 2.5 her At 25 “I3. Ihe eeuilbriurn eenetent is Hen-3"“ fer the deeempeshiear ef fructese-1 .fi- diphesphete [FDFl te ferrTI glyeEreHenyde-E-pheephete [Ge-F] end dihyeresyeeetene pheephete [EIHAF']. FDF' = UHF“ + DHFtF'. {e} SLer'tlrt-g et an initial eehcentretren ef I11 hi FDP {eefere eeeentpeertient, celeulete the eeecerttretiees er I—DP. GAP erte L1H.-=i.l-1 et equilibrium. Perferm the eelcutet. en ti] with nD simplifying assumptiene. iii] with the simplifying ere-eurrrptierr that reletIt-ely little FDF' cleeempeses. {Is} Repeat the ebeue calculefie ne fer an initial ceneentreLien Di “II‘ICI'E' M F'DF'. [ct Determine the Gibbs energy change fer the reectien fer EGAF‘FU'J HAF1=2I1D i' M and [FeF]=-:I.e M- . E? El- Fer the equilibrium reaetien. A = El. the uan't Hefi plat [lntli] are. 1:01 below was ebtained Caleulate arH" and ms: fer thia- reaelien. 15 ' fi-u ......_._...._. E 5. |n[l{} 3.0 0.0045 0.005 1 r T [W] 0.004 31-1 9.5 we learned in claea, the auerege number Elf liganda be und in a protein. H. is related tn the ligand eeneentretian, [L]I by the relation: _. r'I1Ll mm [L] where n ie the maxim um number at lee-ulna Jiga rlde and Hi ia the average dieenniafim eeneta nt. A prete'ln binds a llgand {a.g. Ca2+} uia the D'u'EiEII' equilibrium F' + TIL = F'L..-: With 1'03 average diaaeeietian eenatant. it. A pair at equilibrium dialy‘aie experimenta wane EIEch-n'l'red with a tetah pretaln eaneentratien. [P]..,1 = 0.004 M. [ii When [L]w.“,=u 110 M, [L] ,.,dfl=0_2tt M. {23 When {L]m.m=0.020 M [lefiflfi'fifi- I'ul. Caleulata the total maximum n u mtler of attached ligands. n. and the average dieseeiatien mnatant. K. 57-25 Fur a typififll ligand Ending expefimenl. a plot I:-f NH 1'3. 1."[L] [H ug nearl'llcflz plat} yieldeni the graph bEIDI'I'. Ealculate n and P: fun this prGt-ein liga nd system. llflfifl ELIJEE 11.1151] HR [H145 M4111 ELD 1.IJ El:- 3.D LI] 5.1] * “[L] m": SIB The reactinn far the nveral'. Elyunlysifi reactiurl is: Glucnfia + 2MB‘ + EADP - F" —1~ E EHafiflE'flz + EMF-DH + EATF’ + 1| 1* The Hiulugififil ChEl‘niE1W Standard Stat-a Ruactiun Gibb-5 Energy change i5' M?" = -HI:I.T kJ. Galculam the Frthrt-fllza'lF Ghemisiry Slandard State Heactinn Gibbs En argy- mange: M3". ...
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HWQ-Chap-7-3530 (1) - CH4 . "Fe Hm fiwé‘m e at...

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