Unformatted text preview: h) [M(CO) 4 I(dppe)]-(dppe = 1,2-bis(diphenylphosphino)ethane). 4 . Determine the metal-metal bond order consistent with an 18 electron count for the following: a) [( η 5-Cp)Fe(CO) 2 ] 2 ; b) [( η 5-Cp)Mo(CO) 2 ] 2 2-5 . On the basis of the 18 electron rule, determine the expected charge on the following: a) [Co(CO) 3 ] z ; b) [Ni(CO) 3 (NO)] z (contains linear NO); c) [Ru(CO) 4 (CMe 3 )] z ; d) ( η 3-C 3 H 5 )V(CNCH 3 ) 5 ] z ; e) [( η 5-Cp)Fe(CO) 3 ] z ; f) [( η 5-Cp) 3 Ni 3 ( μ 3-CO) 2 ] z 6 . Propose synthetic routes for the following: Pt Cl H 3 N Cl Cl Pt Br H 3 N py Cl Pt Cl Cl Cl Cl Pt Cl O 2 N Cl py 2-a) b) 7 . Account for the observation that two separate water exchange rates are found for [Cu(OH 2 ) 6 ] 2+ in solution....
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This note was uploaded on 04/17/2011 for the course CHEM 273 taught by Professor Levine during the Spring '09 term at UCLA.
- Spring '09