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Unformatted text preview: X k (M-1 s-1 ) F Cl Br NCS N 3 1.2 x 10-3 11 60 1.2 x 10-4 (at 24 °C) > 1.2 4 . Is the reaction [Co(NH 3 ) 6 ] 3+ + [Cr(OH 2 ) 6 ] 2+ likely to proceed by an inner-sphere or outer-sphere mechanism? Explain your answer. 5 . Predict the products of the following reactions: 6 . The complex shown below loses CO on heating. Would you expect this CO to be 12 CO, 13 CO, or a mixture of both? Why? 2 7 . Identify each of the reactions in the transformation below as oxidative addition, reductive elimination, ligand dissociation, etc. Some of the reactions are not the elementary steps. For those processes show each step....
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- Spring '06
- Chemistry, rate constants, high-spin d4 complex, low-spin d4 complex, Br NCS N3