chem14D-exam1-review-1

chem14D-exam1-review-1 - Chem 14D Spring 2010 Garg Midterm...

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NKG 4/19/10 Chem 14D – Spring 2010 – Garg Midterm 1 Review / Practice Problems Some Topics to Study (very broad): Reactivity stuff Classify atoms as electrophilic or nucleophilic Definitions of nucleophiles/electrophiles Nucleophiles Leaving groups Solvent types pKa of common acids Steric hindrance Arrow-pushing S N 2 Mechanism Stereochemistry Transition state Reaction coordinate diagram Inter and intramolecular examples Solvent trends / solvation S N 1 Mechanism / solvolysis Stereochemistry Transition state Reaction coordinate diagram Solvent trends E1 and E2 Mechanisms Stereochemistry Solvent/reaction condition trends Alcohol Synthesis Nucleophilic additions to carbonyls NaH vs. NaBH 4 / LiAlH 4 Organolithium reagents / Grignard reagents Oxidation / chromium reagents Retrosynthetic analysis PRACTICE QUESTIONS…
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NKG 4/19/10 1. Consider the following solvents. For each, draw the structure and circle the appropriate solvent classification. a) isopropanol Structure: Classification: (Circle one answer) polar, protic polar, aprotic nonpolar, aprotic b) DMF Structure: Classification: (Circle one answer) polar, protic polar, aprotic nonpolar, aprotic
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chem14D-exam1-review-1 - Chem 14D Spring 2010 Garg Midterm...

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