answers Homework 5 (Elementary&SteadyState)

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Unformatted text preview: CHEMISTRY 1008 Name: i '36:? Homework Assignment #5 Due: Thursday, March 3 (it will be much more helpful to finish this before prelim #1) l. (4 pts) Give the rate law for each of the following elementary reactions: (a) 03(g) + Cl(g) -> 02(g) + C10(g) Fair. = l: [03] [Cl] (b) N02(g) - Org) + Noe) mm: L [N023 (c) org) + Clorg) + org) + Clrg) rm z k {03 [cm] , Q. (d) We) + Cl(g) +c1(g) -> N2(g) + 012(g) m to = k £er [cl] W 2. (3 pts) The thermal decomposition of 11in1 chloride, NOZCI, is believed to occur by the following mechanism k1 N02C1(g) -+ N02(g') + Cl(g) k2 Cl(g) + N02Cl(g) —’ N02(g) + C12(g) (a) What is the overall reaction? ,ZNblCl ('3) ___~? 2N0; (:1) + Cl; [3) (b) What rate law is predicted by this mechanism if the first step is the rate-determinin ste ? NQLM .5.» we; +-C\ (S'OW) ("h C: U r' N09.“ £5 NQ1 1'01 (Cast) , rod-c: k! [It/Olen ”Fate chnrmcnj (st-(f 3. (3 pts) The reaction, 2N02(g) + F2(g) -> 2N02F(g), has a second order rate law: rate = k[N02] [F21 Suggest a mechanism that is consistent with this rate law. -___ ‘--———.___n i, , .— ‘H‘Lftl'é‘ ‘MO&(I9) 1— Fly)” ‘LL NUDIF (3) “r FCQ) (Stall) 9592:. Nola) rm) ~—-‘—> MOAFt‘D (9.5+) _....—- Slow 50 ROS Ma“— OV-Crull: QNOJ‘D t F165) '*—> QNQAFCGJ) R TR“, mtlbafl-‘SM I i - ‘ “HM bo’fl‘ 14““ A m Fork: L, “’0ijij 9/ :W:“ (“Wm M; W (“HI lam/I Clue My bffiwfiiw§ ...
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