Ch 23 Exercises

Ch 23 Exercises - Exercises

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Exercises 23.1a    Derive the  rate law  for the decomposition of ozone in the reaction 2 O 3 (g)   3 O 2 (g)  on the  basis  of the following proposed mechanism: 23.1b   On the  basis  of the following proposed mechanism, account for the experimental fact  that the  rate law  for the decomposition 2 N 2 O 5 (g)   4 NO 2 (g) + O 2 (g) is v =  k [N 2 O 5 ]. 23.2a   A slightly different mechanism for the decomposition of N 2 O 5  from that in Exercise  23.1b has also been proposed. It differs only in the last step, which is replaced by Show that this mechanism leads to the same overall  rate law 23.2b   Consider the following mechanism for the thermal decomposition of R 2 : where R 2 , P A ,P B  are stable hydrocarbons and R and R  are radicals. Find the dependence of   the rate of decomposition of R 2  on the concentration of R 2 23.3a   Refer to  Fig. 23.3  and determine the  pressure  range for a branching chain explosion  in the hydrogen–oxygen reaction at 800 K. 23.3b
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Ch 23 Exercises - Exercises

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