CheatSheet3

# CheatSheet3 - Food For Thought Kp = KcRTng KP(T2 ln K =...

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Food For Thought K p = K c RT ng K p = K x P ng K p = x 2 a 2 -x 2 P ln K P(T2) K P(T1) = - r H o - R 1 T 2 - 1 T 1 ln K P(T2) K P(T1) = - r H o o - R ( 1 T 2 - 1 T 1 ) + a R ln T 2 T 1 + b 2R (T 2 - T 1 ) + c 6R (T 2 2 - T 1 2 ) ln K P = ln K P (0) - r H o o - RT + a R ln T + b 2R T + c 6R T 2 f G o -' = f G o - + RT ln 10 -7 ln [A] [A] o = - k 1 t [A] = [A] o e -k 1 t [B] = [A] o ( 1 - e -k 1 t ) 1 [A] - 1 [A] o = k 2 t 1 b-a ln a(b-x) b(a-x) = k 2 t ln [A] o -[A] eq [A]-[A] eq = (k 1 + k -1 ) t [B] = k 1 [A] o (k 1 + k 2 ) ( 1 - e -(k 1 +k 2 ) t ) [C] = k 2 [A] o (k 1 + k 2 ) ( 1 - e -(k 1 +k 2 ) t ) [B] = [A] o k 1 k 1 '– k 1 () e -k 1 t - e -k 1 't [C] = [A] o 1 + 1 k 1 – k 1 ' k 1 ' e -k 1 t - k 1 e -k 1 't dP dt = k 2 k 1 [RX] [Nuc: - ] k -1 [X - ] + k 2 [Nuc: - ] d[P] dt = k 1 [E] o [S] (k M + [S]) k M = ( k 1 + k -1 ) k 2 d[B] dt = k 1 k 2 [A] 2 k -2 [A] + k 1 τ = 1 k -1 + k 1 ([A] eq + [B] eq ) x = x o e –t/ τ ( x = [C] ) τ = 1 k 1 + k -1 k = A e -E a/RT ln k (T2) k (T1) = - E a R ( 1 T 2 - 1 T 1 ) μ(M p X q ) = μ o - (M p X q ) + RT ln γ n ± m p + m q m o - n γ ± = ( γ p + γ q - ) 1 / n I = 1 2 z 2 i m i m o - sol G = VdW G + cav G + elec G V(r) = q j q i 4 πε o ε r r V(r) = φ i q i w elec = 0 Z i e φ i dq p(r) dr = 4 π r 2 N o e - φ i (r)q j kT dr κ = 2 e 2 1000 L m -3 d N A ε r ε o kT I 1/2 r D = 305 pm (c/mol L -1 ) ½ = 1 κ elec G = w sol N A – w vac N A 2 φ i (r) = - ρ i (r) ε (r) 2 (r φ

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## This note was uploaded on 05/01/2011 for the course CHEM 345 taught by Professor Cardelino during the Fall '09 term at Spelman.

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CheatSheet3 - Food For Thought Kp = KcRTng KP(T2 ln K =...

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