Topic_3.5_AMINE_AMIDE - 3 CH 3 CH 3 NH 2 + + + H Cl...

Info iconThis preview shows pages 1–25. Sign up to view the full content.

View Full Document Right Arrow Icon
Derivatives of hydrocarbons Amines and Amides Chapter 3.5 Amines Structure and Properties Amine Nomenclature Heterocyclics Amines Amine Sources Basicity of Amines Reactions of Amines Importants of Amines Amides
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Alkylamine N attached to alkyl group Arylamine N attached to aryl group
Background image of page 2
Amine nomenclature Primary amines Locate longest carbon chain that contains -NH 2 group. Use the hydrocarbon name, drop –e , replace with –amine . Assign location of amine group so that the lowest possible number is used. Name and number any side chains or other groups.
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
1-propanamine 2-propanamine 2-hexanamine
Background image of page 4
Background image of page 5

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 6
N-methyl-1-propanamine N,N-dimethylcyclohexanamine
Background image of page 7

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
N-ethyl-N-methylethanamine 1,2-propanediamine
Background image of page 8
Background image of page 9

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 10
Have fishy smell. BP & MP higher than alkane but lower than alcohol.
Background image of page 11

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
methanamine 1 ° amine N-methylmethanamine 2 ° amine N,N-dimethylmethanamine 3 ° amine methanal
Background image of page 12
butanamide 1-butanamine nitrobenzene aniline 1. LiAlH 4 2. H 2 O or H 2 , Ni methanol 1. Fe, HCl 2. NaOH
Background image of page 13

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Reaction of amines react with acid chloride to form amide RCCl O + + + R C O NHR' R’NH 2 + + + H Cl acid chloride amide example CH 3 CCl O + + + C O NHCH
Background image of page 14
Background image of page 15

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 16
Background image of page 17

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 18
Background image of page 19

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 20
Background image of page 21

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 22
Background image of page 23

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Background image of page 24
Background image of page 25
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: 3 CH 3 CH 3 NH 2 + + + H Cl methanamine methanoyl chloride N-methylethanamide Derivatives of carboxylic acids where an amino (-NH 2 ) group replaces the OH group. O O || || CH 3 COH CH 3 CNH 2 carboxylic acid amide ethanoic acid ethanamide Amides R C O NH 2 General formula O || HCNH 2 O || CH 3 CNHCH 3 O || CH 3 CH 2 CN(CH 3 ) 2 Examples C O NHCH 3 methylbenzam ide-N methanamide-methylethanamide N,N-dimethylpropanamide Properties of amides appearance: solid at room temperature smell like rat or unpleasant smell high boiling point Simple amide soluble in water propanoic acid propanamide benzoyl chloride benzamide acid hydrolysis O HCl + H 2 O || O CH 3 COH + NH 4 + Cl || CH 3 CNH 2 O NaOH || CH 3 CO Na + + NH 3 base hydrolysis Reaction of amides ethanamide ethanoic acid sodium ethoxide Ammonium chloride N CH 3 Nicotine, leaves oftobacco plant N N N N CH 3 O O CH 3 CH 3 Caffeine,coffee beans and tea...
View Full Document

This note was uploaded on 05/08/2011 for the course ACCOUNTING 121210 taught by Professor Sdasdas during the Spring '10 term at Albany College of Pharmacy and Health Sciences.

Page1 / 25

Topic_3.5_AMINE_AMIDE - 3 CH 3 CH 3 NH 2 + + + H Cl...

This preview shows document pages 1 - 25. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online