Copy of Solvolysis tbcl 1412.xlsx 02-1

Copy of Solvolysis tbcl 1412.xlsx 02-1 - tButyl Chloride...

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Unformatted text preview: tButyl Chloride Concentration vs Rate of Solvolysis Concentration Effects tBuCl Exp Vol tBuCl Moles tBuCl [tBuCl] 1 1 0.01 0.18 2 2 0.02 0.36 3 3 0.03 0.53 time 1 (sec) = 44.81 pH@time 1 ln[tBuCl] = X 1.73 1.03 0.63 1 2 3 time 2 (sec) = 1 2 3 time 3 (sec) = 1 2 3 4.04 3 2.82 [tBuCl] reacted at time 1 = 10pH Rate = [tBuCl]/t1 ln(Rate tBuCl)1 0 0 0 0 0 0 13.1 10.7 10.3 106.46 pH@time 2 2.87 2.44 2.29 [tBuCl] reacted at time 2 = 10pH 0 0 0.01 Rate = [tBuCl]/t2 0 0 0 ln(Rate tBuCl)2 11.27 10.28 9.93 172.54 pH@time 3 2.55 2.17 2.02 [tBuCl] reacted at time 3 = 10pH 0 0.01 0.01 Rate = [tBuCl]/t3 0 0 0 ln(Rate tBuCl)3 11.03 10.14 9.8 ln(Rate tBuCl)1 ln(Rate tBuCl)2 = ln(Rate tBuCl)3 = ln(Rate) at ln[conc]= 0 = lnk ln[tBuCl] = X = Y1 Y2 Y3 1.73 13.1 11.27 11.03 8.37 1.03 10.7 10.28 10.14 9.04 0.63 10.3 9.93 9.8 9.1 8.8 k=eln(Rate) 1.E04 Solvolysis tBuCl 0 -2 -4 -6 -8 -10 f(x) = 2.65x - 8.37 1.13x 9.04 1.24x 9.1 -12 -14 -1.8 -1.6 ln [BuCl] -1.4 -1.2 ln (Rate) -1 -0.8 -0.6 -0.4 -10 f(x) = 2.65x - 8.37 1.13x 9.04 1.24x 9.1 -12 -14 -1.8 -1.6 -1.4 -1.2 ln (Rate) -1 -0.8 -0.6 -0.4 ...
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