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CBE 102B Problem Set 1 [ABET] Due: Friday, April 9, 2010 1. (40 pts.) Consider a fluid that obeys the van der Waals equation of state 2 1 , mm RT pa Vb V =− − where is the molar volume. For this fluid, , , , , and can be expressed in the following form m V m U Vm C m H pm C m S () ( )( ) () ( )() () ()() (o) 1 2 3 5 ,, m m m Vm Vm m Vm m m m m m m UUV TUT f V T CCV TCTf V T HH V THTf V T S S VT S VT fVT == + + + == + , where is the molar property of an ideal gas at temperature T and molar volume . The functions
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This document was uploaded on 05/27/2011.
- Spring '11