Lecture Notes_03_30_11_CHM4272

Lecture Notes_03_30_11_CHM4272 - muc—wman—aufl 1:8...

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Unformatted text preview: muc—wman—aufl 1:8 2:53 5.33:6 F/T‘ ”\\#\\ cup“ ‘ / /\\ _;, “T1 —— on», \ i ’ Aur'" C\r\30'T Afr ..___.. /— 1 x—g/ \ oo 5 L 5 ~——-7 \mo ___‘5_ \\ wa‘ Eh-ufla- A ‘33 H h‘:\ VG? Energy Levels: 1t Molecular Orbitals for Polyacetylene Tr Systems of CH —(CH); *(CH); 1r*— — 4_k 7’ H fl (0mg «Hr—6 I llllllll :1: i i :1: iiiiiiii —(CH); Uniform Alternating C—C Bond Order 0—0 Bond Order m D --¢$iiii¢#it;ll||l_l|ll|l------- --iiiiiiiiiiiil l | || | | | | | l G=neu 6 = conductivity (9 -1 cm-1 or Scm-1) n = # of carriers e = carrier charge carrier mobility u Con &“‘¢4{I'.b Q . A ‘2. CM .3. CWL 7' JL'F‘ (iv-5" :' s/th CONDUCTIVITY (52" cmf‘) :04 I03 IO IO 0.05 O.-IO OJ 5 CONCENTRATION , 5! 0.20 0.25 LOGO I} LOG Y IN CH(CIO4)Y_ .5 .R .32 .33 Sim 253582 $9". 52886me 3:25.23: wEEEoEm ho cog—.3053 :oqxz >9 3.39:". . mEE mEucfiw 3E . 23382.”. cam 83... .222 n9.22.“: 29:8 >29... . :wmmm ¢:_U_w._0_.:m: mz_.=2<>._0n_ ._<m_._.3mz PERCENTAGE DOPING (y) Salaneck, Lundstrom, Huang and MacDiarmid Synth. Met. 1986, 13, 291. ...
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Lecture Notes_03_30_11_CHM4272 - muc—wman—aufl 1:8...

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