Unformatted text preview: ( 29 ( 29 ( 29 ( 29 , , j j E V pV H V kT kT j j N p T e dV e dV + âˆž âˆžâˆ† = = âˆ‘ âˆ‘ âˆ« âˆ« , where we used the fact that the Volume is a continuous variable and thus we can replace a the Î£ v by an integral c. Evaluate the average Enthalpy <H> (write as a function of Z(N,p,T) d. Evaluate the average Volume <V> (write as a function of Z(N,p,T) 2. McQuarrie 3.20 3. For an ideal gas, with N=0.001 moles. Calculate the probability of observing a spontaneous fluctuation in energy =103 . <E>...
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This note was uploaded on 05/29/2011 for the course CHM 6461 taught by Professor Bowers during the Spring '08 term at University of Florida.
 Spring '08
 Bowers

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