Chapter 15 Su09SC

Chapter 15 Su09SC - Organic Chemistry 5th Edition Paula...

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Chapter 15 Reactions of Substituted Benzenes Organic Chemistry 5 th Edition Paula Yurkanis Bruice
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Nomenclature of Disubstituted Benzenes Numbers or prefix can be used to indicate position of substituents. Substituents are alphabetized with benzene as the name of the parent hydrocarbon. Section 15.1
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Nomenclature of Disubstituted Benzenes If one of the groups can be incorporated in the name of the molecule, it is. That group is attached to carbon 1. Cl CH 3 NH 2 NO 2 OH CH 2 CH 3 Section 15.1
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Nomenclature of Polysubstituted Benzenes Br CH 3 NO 2 Cl Br OH CH 2 CH 3 NH 2 I Br Cl Cl Section 15.1
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Bromination of Substituted Benzenes NO 2 + FeBr 3 Br 2 CH 3 + FeBr 3 Br 2 CH 3 CH 3 Br Br + NO 2 Br Section 15.3
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Why directing effects? Section 15.1 CH 3 Br 2 , FeBr 3 CH 3 Br H CH 3 Br H CH 3 Br H Resonance contributors leading to ortho product Br 2 , FeBr 3 CH 3 Resonance contributors leading to meta product Br H CH 3 Br H CH 3 Br H CH 3 Resonance contributors leading to para product H Br CH 3 H Br CH 3 H Br Br 2 , FeBr 3
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Why directing effects? Section 15.1
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Chapter 15 Su09SC - Organic Chemistry 5th Edition Paula...

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