Chapter 16 Lecture NotesSC

Chapter 16 Lecture NotesSC - Organic Chemistry 5th Edition...

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Organic Chemistry 5 th Edition Paula Yurkanis Bruice hapter 6 Chapter 16 Carbonyl Compounds I: Nucleophilic Acyl Substitution
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lass I Carbonyl Compounds Introduction Class I Carbonyl Compounds • Class I carbonyl compounds react with water to produce a carboxylic acid. O O H 3 C Cl H 3 C OH H 3 C Br O H 3 C O O CH 3 O O O CH 3 H 3 C O CH 3 H 3 C N H
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ore Definitions Introduction More Definitions carbonyl compound is one A carbonyl compound is one that contains a carbonyl group. • An acyl group consists of a carbonyl group attached to an alkyl or aryl group. O O
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elative eactivities Section 16.6 Relative Reactivities • Class I carbonyl comopunds can be thought of as containing nd cyl roup and a leaving group (Table 16 1 page 724) and acyl group and a leaving group (Table 16.1, page 724) Compound Compound L.G. L.G. p K a p K a H 3 C Br O H 3 C OH O Br OH H C Cl O O CH 3 Cl OCH 3 3 O O H 3 C O O O H 3 C O CH 3 H 3 C N H CH 3 O CH 3 NHCH 3
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How Class I Carbonyl Section 16.5 Compounds React O +H 2 O O + HCl H 3 C Cl H 3 C OH
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cyl alides Section 16.8 Acyl Halides Acyl halides are the most reactive class I compounds because they have the best leaving groups.
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This note was uploaded on 05/31/2011 for the course CHEM 3341 taught by Professor Staff during the Spring '08 term at Georgia Southern University .

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Chapter 16 Lecture NotesSC - Organic Chemistry 5th Edition...

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