midterm2_sp07 - 1[7 points Which of the following molecules...

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1. [7 points] Which of the following molecules will not have a geometric isomer? (a) (b) (c) (d) 2. [7 points] When an ethylenediamine ligand coordinates to a metal cation, which atoms in the ligand make bonds to the metal? 3. [7 points] Which of the following complexes will be diamagnetic? 4. [7 points] Consider the following three molecular orbitals from the linear BeH 2 molecule? Which of these molecular orbitals will have the highest energy? (a) MO #1 (b) MO #2 (c) MO #3 (d) MO #1 and MO #2 will have the same energy (higher than MO #3) H–Be–H H–Be–H H–Be–H MO #1 MO #2 MO #3
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5. [7 points] Which of the following complexes will have the smallest crystal field splitting energy, Δ . 6. [7 points] What is the correct name for the compound [Rh(NH 3 ) 4 Cl 2 ]Cl a. Rhodium(III) tetraamminedichloro chloride b. Tetraammoniadichlororhodium(III) chloride c. Tetraaminedichlororhodium(III) chloride d. Tetraaminetrichlororhodium(III) e. Dichlorotetraaminerhodium(III) chloride 7. [7 points] Which of the following equations represents the reaction that can be used to prepare nickel(II) vanadate by solid state reaction?
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