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Exam3KEY - Sessler CH310M/CH318M SP 11 Exam 3 Initials 1...

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Unformatted text preview: Sessler CH310M/CH318M SP 11 Exam 3 Initials_____ 1 Please circle the section in which you are enrolled: 310M 318M K E Y Please write the first three letters of your last name in the above boxes Organic Chemistry I Exam III Dr. Jonathan L. Sessler - CH310M/CH318M April, 21 st 2011 Name:_______________________________ UT EID:______________________________ Signature:____________________________ Sessler CH310M/CH318M SP 11 Exam 3 Initials_____ 2 1. For the free radical mono-chlorination of propane, write a complete mechanism using curved “fishhook” arrows and the following guidelines (20 points). Cl 2 , h Cl Initiation: Cl Cl Cl Cl Propagation: H Cl HCl Cl Cl Cl Cl Other steps possible...but do not lead toward the production of the final product. Termination: Cl Cl Cl Cl Cl Cl Sessler CH310M/CH318M SP 11 Exam 3 Initials_____ 3 2. Fill in the boxes with the correct product formed in each reaction. If no reaction occurs, put NR in the box (18 points). NBS h Br 2 HBr HO OH OH HBr OH Me PBr 3 HO H 2 CrO 4 H 2 O, Acetone h Br Br Br Br Br Me NR Sessler CH310M/CH318M SP 11 Exam 3 Initials_____ 4 3. Fill in the reagents that will cause the transformations drawn below. If no reagents will complete the reaction then write NR (18 points)....
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Exam3KEY - Sessler CH310M/CH318M SP 11 Exam 3 Initials 1...

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