ReviewSheet3 - N 1 and S N 2 b Kinetics c Stereochemistry d...

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Review Sheet - Exam 3 Spring 2011 TOPICS: 1. Radical reactions and mechanisms a. Radical structure and stability b. Radical chain reaction mechanisms (initiation, propagation, termination) c. Free radical halogenation (Hammond's Postulate) d. Allylic halogenation e. Addition of HBr to an olefin f. Autooxidation g. Ozone depletion h. Tin hydride reductions and addition of radicals to double bonds i. Synthesis of organometallic reagents Alkyl lithiums Grignard reagents Gilman reagents j. Reactions of organometallic reagents Deprotonation Substitution 2. Nucleophilic Substitution a. Mechanisms (S
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Unformatted text preview: N 1 and S N 2) b. Kinetics c. Stereochemistry d. Effect of nucleophile (trends and predictions) e. Effect of electrophile (steric and electronic effects, rearrangements) f. Solvent effects g. Neighboring group participation h. Synthesis and use of sulfonates 3. Elimination a. Mechanisms (E1 and E2) b. Kinetics c. Regiochemistry (Zaitsev) d. Stereochemistry (olefin geometry) 4. Reactions of alcohols a. Reactions with HX b. Reaction with PBr 3 c. Reaction with SOCl 2 d. Use of sulfonates for the synthesis of iodides...
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This note was uploaded on 07/02/2011 for the course CHEM S341 taught by Professor Staff during the Spring '11 term at Indiana.

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ReviewSheet3 - N 1 and S N 2 b Kinetics c Stereochemistry d...

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