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Unformatted text preview: (Autooxidation) Sulfides preparation and oxidation (sulfoxides and sulfones) Protecting Groups know the conditions for formation and removal of the following protecting groups: t-butyl ethers, THP ethers, benzyl ethers, trityl ethers, silyl ethers Preparation and Reactions of Epoxides Preparations Using peracids, From halohydrins. Stereoelectronic effects. Reactions Nucleophilic ring opening; Acid-catalyzed ring opening Regiochemical and stereoelectronic effects Organic synthesis Multi-step sequences C-C bond forming reactions Functional group transformations and equivalencies Use of protecting groups Arenes Aromaticity and aromatic stabilization- structural requirements Polycyclic aromatics. Heterocyclic aromatics 4n+2 Rule Predicting aromatic vs. antiaromatic structures Basic Frost Diagrams...
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