Exam 4 Tutorzone Key - 4-0852 O H H Pro-S Pro-R N H Re Si...

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www.tutoringzone.com CHEM 2211 Exam 4 Fall 2009 "#$%&'%( "#)*+(,- !"#$%&#
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!" %" 8/55-&7*8 /0)- ! ;& -, *)+%0-& /5 :@"A9 %) !B ';" C+%) /5 /)D5 5<*'/,/' 6-)%)/-0E 4" =6-,*55-6 F0%<* 5%G5 )+* 5<*'/,/' 6-)%)/-0 -, 7*6/)%5*6(; /5 HA"@" ?-0 )(605 /0 % !B1 5%;<&* /0 9;& -, *)+%0-& )+%) +%5 %0 -45*67*8 6-)%)/-0 -, HIB ./)+ % <%)+&*01)+ -, @B';" J/8 +* ,('K (<E HIBLM@ N M!BL9OO P H:"9 Q*5R +* ,('K*8 (<"
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@" $/6'&* )+* '+/6%& '*0)*65 -0 )+* ,-&&-./01 ; Limonene HO Carveol H N O OH N H O HO biphenylalanine N O O N O H O 2-(5-ethyl-2,6-dioxopiperidin-3-yl)-5-(1- hydroxyethyl)isoindoline-1,3-dione OH
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I" ( S )-1-chloro-3-methyloctane ( S )-1,1,3-trimethylcyclohexane ( R )-3-(iodomethyl)heptane 1-((2 S ,3 S )-3-chloro-2-ethylpentyl)-2-methylcyclopropane ( R )-4-(bromomethyl)-2-methylheptane ( S )-3-fluoro-2,3-dimethylnonane Cl I Cl Br F
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Unformatted text preview: 4-0852 O H H Pro-S Pro-R N H Re Si Re Si H H Pro-R Pro-S 9" F+-. )+* ;*'+%0/5; ,-6 )+* ,-&&-./01 5G0)+*5/52 + O NC OH O OH CN A" U5/01 %0G %&KG&+%&/8* 0*'*55%6GR <6-<-5* % 5G0)+*5/5 <%)+.%G )- @[email protected] 8/;*)+G&+*<)%0* ,6-; 4()H!H*0*" OH Br Li + LiX Cu Li + + LiI 1) BH 3 , THF 2) H 2 O 2 , OH-PBr 3 Ether 2 Li Pentane CuI Ether Br Ether 2,2-dimethylheptane but-1-ene :" J*)*6;/0* )+* ;/55/01 6*%')%0)R 6*%1*0) -6 <6-8(')R %08 /08/'%)* /, )+* <6-8(') /5 -<)/'%&&G %')/7* -6 0-)2 Cl KOH No H F H 1) Mg, Ether 2) H 3 O + No Br SnBu 3 Catalytic amounts of Pd(Ph) 4 /LiCl No OH HCl 0 C Cl No OH PBr 3 Ether Br Yes Br NBS CCl 4 H Yes HBr Ether Br No Br No HBr Ether V" =6*8/') %&& )+* <6-8(')5 ,-6;*8 ,6-; )+* ,-&&-./01 %88/)/-0 6*%')/-05 M./)+ W$& /0 *)+*6OR %08 '/6'&* )+-5* )+%) %6* ;-6* <6*5*0) (08*6 )+*6;-8G0%;/' '-0)6-&2 HCl Ether Cl Cl Cl Cl Cl Cl...
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This note was uploaded on 07/18/2011 for the course CHEM 1212 taught by Professor Suggs during the Spring '08 term at University of Georgia Athens.

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Exam 4 Tutorzone Key - 4-0852 O H H Pro-S Pro-R N H Re Si...

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