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EQUATIONS POLYMER PHYSICS

EQUATIONS POLYMER PHYSICS - Equations for Polymer...

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Unformatted text preview: Equations for Polymer Physics/Processing Rubber Elasticity: ( 29 σ λ λ =-- N kT V 2 ( 29 σ ρ λ λ =- -- RT M M M C C o 1 2 2 ( 29 σ ρ ϕ λ λ =-- RT M C 1 3 2 ( 29 σ λ λ λ 3 2 x N kT v x x y =--- σ ρ ϕ λ λ 1 3 2 1 x c x x RT M = - / σ ρ λ λ 2 1 x c x x RT M = - ( 29 σ λ λ =- -- f f N RT V * * 2 2 σ = ( 29 f f N RT r r v i * *- -- 2 2 2 2 λ λ V T V T l S T l E f , , ∂ ∂- ∂ ∂ = V l V T T f T l E f , , ∂ ∂ + ∂ ∂ = P = 4 1 3 7 d N kT R v λ λ λ *- ∆ S N k c = - 2 [ ( ) (ln( )) λ λ λ λ λ λ x y z x y z 2 2 2 3 + +- + ] Thermodynamics of Mixing ( 29 2 1 2 2 / 1 2 2 2 / 1 1 1 υ υ ∆ + ∆ = ∆ V E V E V H m m T k N H m 2 , 1 2 1 χ υ = ∆ ( 29 + - +- = ∆ 2 2 1 2 2 1 1 1 ln υ χ υ υ x RT G mix ( 29 2 2 1 1 1 2 , 1 δ δ...
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EQUATIONS POLYMER PHYSICS - Equations for Polymer...

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