Lecture 13

Lecture 13 - Welcome to Chemistry 120A Lecture 13 Molecular...

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Unformatted text preview: Welcome to: Chemistry 120A Lecture 13 Molecular Orbital Diagrams for Transition Metals and Reaction Types Prof. Joshua Figueroa Molecular Orbital Structure of Transition Metal Containing Complexes x z y Ni H H H H 2- Molecular Orbital Structure of Transition Metal Containing Complexes E 2C 4 σ h 2S 4 2 σ v D 4h red A 1g 1 1 1 1 1 1 E u 2-2-2 4 2 C 2 C 2 ' C 2 " i 2 σ d 4 2 B 1g 1 1 1 1 2 1-1 1 1-1 1-1 1 1-1- Use Reduction Formula or Intuition - Molecular Orbital Structure of Transition Metal Containing Complexes x z y Ni H H H H 2- E 2C 4 σ h 2S 4 2 σ v D 4h red A 1g 1 1 1 1 1 1 E u 2-2-2 4 2 C 2 C 2 ' C 2 " i 2 σ d 4 2 B 1g 1 1 1 1 2 1-1 1 1-1 1-1 1 1-1- Use Reduction Formula or Intuition - A 1g Salc E u Salcs B 1g Salc Molecular Orbital Structure of Transition Metal Containing Complexes x z y Ni H H H H 2- A 1g E g E g B 1g B 2g z 2 xz yz x 2-y 2 xy MO Diagram for [NiH 4 ] 2- 2s A 1g 3p x 3p y 3p z A 2u E u E u 4H 1s 1b 1g 1e u A 1g + E u + B 1g 1a 1g 5 d A 1g + E g + B 1g + B 2g 2b 1g 2e u 1a 1g 1a 2u 2a 1g 1b 2g 1e g 2s...
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Lecture 13 - Welcome to Chemistry 120A Lecture 13 Molecular...

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