fall07org1e3

fall07org1e3 - OH Br H-Br 6) Draw curly arrows to show the...

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Exam 3 Fall 07 Chapters 9-13 100points N a m e If you do not want your graded quiz placed in the box outside my office, then please tick here 1) Identify the following functional groups. (16pts) RO R RO O R RO H R O H R O OH R O R R O OOH R O OR 2) The following antifungal treatment has made Novartis millions of dollars. (10pts) N CH 3 a) how many carbons are in this molecule ? b) how many sp hybridized carbons ? c) how many sp 2 hybridized carbons ? d) how many π bonds ? e) circle the location of the most reactive π bond. NAME THIS MEDICINE FOR 2 BONUS POINTS. Fall07org1exam3 - 1 -
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3) Give the products (if any) formed in the following reactions: (15pts) 1) 1 equiv. Br 2 2) 1 equiv. Cl 2 1) NaNH 2 2) 3) H 3 O + CC H H 3 C Sia 2 BH H 2 O 2 , NaOH O Ph Ph Na, NH 3 HgSO 4 H 2 SO 4 H 2 O 4) Circle the most acidic Hydrogen in each of these three molecules. (6pts) H H H H H H H H H H H H O H HO CH 3 S O O HO Fall07org1exam3 - 2 -
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5) Draw curly arrows to show the mechanism of the following reaction. (8pts)
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Unformatted text preview: OH Br H-Br 6) Draw curly arrows to show the mechanism of the following reaction. (8pts) OH Br H-Br-----Note that one of these is S N 1 and the other is S N 2-----Fall07org1exam3 - 3 - 7) Name (in IUPAC form) the following two compounds. (8pts) F Br HO 8) Provide the products (if any) in the following reactions. (8pts) Lindlar's Catalyst H 2 Lindlar's Catalyst H 2 Lindlar's Catalyst H 2 Lindlar's Catalyst H 2 Ph Ph Ph Ph Ph Ph H H H H H H H H H H H H Fall07org1exam3 - 4 - 9) Circle the strongest acid of each threesome: (6pts) a) b) OH OH CH 3 OH OCH 2 CH 3 CH 3 CH 2 OH CF 3 CH 2 OH c) O H H CH 3 CH 2 CH 3 CH 2 O H CH 3 CH 2 O 10) Provide reagents to accomplish the following transformations. (15pts) OH OH OCH 2 CH 2 CH 3 Cl O O H Fall07org1exam3 - 5 -...
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fall07org1e3 - OH Br H-Br 6) Draw curly arrows to show the...

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