NIBANS - Nomenclature, Isomerism, Bonding NIB/ALA/P.1...

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Nomenclature, Isomerism, Bonding NIB/ALA/P. 1 92(I)1.(a) (i) COOH COOH COOH COOH COOH COOH (ii) Terylene ( 2 2 1 ) (iii) (b) C C O O O C CH 3 H C 2 H 5 ( 1 ) ( 2 ) 93(I)3.(a) (i) a : sp 3 b : sp c : sp 2 ( 1 2 1 ) (ii) α : 109 ° β : 180 ° γ : 120 ° ( 1 2 1 ) (iii) CH 3 CH 2 CH 2 CH 2 COOH ( 1 ) pentanoic acid ( 1 ) 93(II)9.(c) C Br CH 3 H C 2 H 5 C C 2 H 5 CH 3 H Br ( 2 ) 94(II)7.(a) Structural isomerism – occurrence of more than one structure for a given molecular formula. ( 1 ) e.g. C 4 H 10 CH 3 CH 2 CH 2 CH 3 CH 3 CHCH 3 CH 3 and ( 1/2 ) ( 1 2 1 ) COOH COOH COOH COCl PCl 3 PCl 5 /SOCl 2 HOCH 2 CH 2 OH ( ) n C O C OCH 2 CH 2 O O
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Nomenclature, Isomerism, Bonding NIB/ALA/P. 2 Stereoisomerism – occurrence of more than one configuration ( different arrangement of groups in space ) for a given structural formula ( 1 ) C H F Br CH 3 C C H 3 F Br H ( 1/2 ) 94(II)8.(c) (i) 4,5-dimethylhex-1-ene (ii) propyl butanoate ( 1 × 3 ) (iii) 4-hydroxyhexan-3-one 96(I)3.(c) (i) a : sp 3 b : sp
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This note was uploaded on 08/17/2011 for the course CHEM 100 taught by Professor Fleet during the Fall '08 term at Oxford University.

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NIBANS - Nomenclature, Isomerism, Bonding NIB/ALA/P.1...

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