Chem 261 Exam 2 Sample Test Problems

Chem 261 Exam 2 Sample Test Problems - materials below i n...

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I. Nomenclature Write a correct name (IUPAC or common as indicated) or draw the structure for each of the following. A. IUPAC B. Isoprene C. 2-bromo-4-methyl-2Z, 4E-heptadiene II. Reactions Complete the following reactions by giving the missing reagent(s), starting material(s) or product. If you are giving the product, only give the major organic product A. B. HI I OH OH HO 1
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C. D. OH H CH 3 H 3 C CH 2 CH 2 CH 3 H 3 C CH 3 H CH 2 CH 2 CH 3 1. OsO 4 2. NaHSO 3 1. OsO 4 2. NaHSO 3 *This reaction is stereospecific. Draw the products from the two stereoisomer starting
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Unformatted text preview: materials below, i n d i c a t i n g s t e r e o c h e m i s t r y a t e a c h n e w c h i r a l c e n t e r f o r m e d . E. What is the stereochemical relationship between the two products drawn in E? _______________________________________________________________________ III. Mechanisms A. Write a detailed, stepwise mechanism for the following reaction. Cl 2 H 2 O + H 3 O + + Cl-Cl OH 2...
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This note was uploaded on 08/27/2011 for the course CHEM 101 taught by Professor Smith during the Spring '11 term at East Carolina University .

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Chem 261 Exam 2 Sample Test Problems - materials below i n...

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