chap_18_review

chap_18_review - H 2 O R R' HO OH aldehyde or ketone + HCN...

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S S 1) BuLi 2) R-X 1 0 S S R H 1) BuLi 2) R'-X 1 0 S S R R' H 3 O + HgCl 2 R R' O 1. 2. R C OH O 2R'-Li R C OLi OLi R' H 3 O + R C R' O 3. R C N + R'-Mg-X R C N-MgX R' H 3 O + R C O R' 4. R C Cl O LiAlH(O- t -Bu) 3 (or H 2 , Pd, BaSO 4 , S) R C H O R 2 'CuLi R C R' O 5. R C O R' + R''-MgX R C R' R'' O - H 3 O + R C R' R'' OH R C O R' NaBH 4 or LiALH 4 H + R C R' H OH Ph 3 P R R + - + R' O R' R' R' R R + Ph 3 P=O Chap 18 Review 6. 7. 8. R R' O +
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Unformatted text preview: H 2 O R R' HO OH aldehyde or ketone + HCN R R' HO CN-CN + R'' NH 2 H + R C N R' R'' H 2 O + + N 2 H 4 R C N R' NH 2 KOH Heat R C R' H H + N 2 + H 2 O...
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This note was uploaded on 09/02/2011 for the course CHEM 30b taught by Professor Harrison during the Spring '11 term at West Valley.

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